Synthesis, Crystal Structure, Luminescent Property and DNA-Binding of a Cadmium Complex with 2,4-Bis-oxyacetate-benzoic Acid  

作　　者：郭航鸣 沈伟 陈小菊 赵国良 

机构地区：[1]Jinhua Radio and Television University [2]College of Chemistry and Life Science, Zhejiang Normal University [3]Xingzhi College, Zhejiang Normal University

出　　处：《Chinese Journal of Structural Chemistry》2015年第7期1080-1086,共7页结构化学（英文）

基　　金：supported by the Natural Science Project of Zhejiang Province(LY12B01003)

摘　　要：A complex [Cd2Na2（BOABA）2（H2O）8]·H2O（1） was synthesized by using 2,4-bisoxyacetate-benzoic acid（H3BOABA） and Cd（OH）2. It was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional 3-connected rigid plane. The interactions between the ligand and its complex with DNA were studied by Et Br fluorescence probe. Photoluminescent studies indicate that the complex may be excellent candidates for potential photoactive materials.A complex [Cd2Na2（BOABA）2（H2O）8]·H2O（1） was synthesized by using 2,4-bisoxyacetate-benzoic acid（H3BOABA） and Cd（OH）2. It was characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Complex 1 shows a two-dimensional 3-connected rigid plane. The interactions between the ligand and its complex with DNA were studied by Et Br fluorescence probe. Photoluminescent studies indicate that the complex may be excellent candidates for potential photoactive materials.

关 键 词：Cd complex 2 4-bis-oxyacetate-benzoic acid crystal structure DNA-BINDING photoluminescence 

分 类 号：O621.2[理学—有机化学]