Synthesis and characterization of a tetradentate PNCP iridium complex for catalytic alkane dehydrogenation  

作　　者：Xiangqing Jia Zheng Huang 

机构地区：[1]State Key Laboratory of Organometallic Chemistry [2]Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences

出　　处：《Science China Chemistry》2015年第8期1340-1344,共5页中国科学（化学英文版）

基　　金：financially supported by the National Basic Research Program of China(2015CB856600);the National Natural Science Foundation of China(21422209,21432011,21421091)

摘　　要：A novel hydrido iridium chloride complex supported by a tetradentate PNCP ligand has been synthesized and characterized. Upon activation with NaOtBu, the PNCP-IrHC1 complex is active for transfer dehydrogenation of cyclic and linear alkanes.A novel hydrido iridium chloride complex supported by a tetradentate PNCP ligand has been synthesized and characterized.Upon activation with Na Ot Bu,the PNCP-Ir HCl complex is active for transfer dehydrogenation of cyclic and linear alkanes.

关 键 词：ALKANE DEHYDROGENATION IRIDIUM tetradentate ligand 

分 类 号：O641.4[理学—物理化学]