Si@Cu@Au AFM tips for tip-enhanced Raman spectrum  

作　　者：Pei Lu Jing Li Dong Wang Li-Jun Wan 

机构地区：[1]CAS Key Laboratory of Molecular Nanostructures and Nanotechnology [2]Institute of Chemistry, Chinese Academy of Sciences [3]Beijing National Laboratory for Molecular Sciences

出　　处：《Science China Chemistry》2015年第9期1494-1500,共7页中国科学（化学英文版）

基　　金：supported by the National Basic Research Program of China(2011YQ03012415,2011CB808700);the National Natural Science Foundation of China(21127901,233010,21121063);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12020100)

摘　　要：Tip-enhanced Raman spectrum(TERS) is a scanning probe technique for acquiring chemical information at high spatial resolution and with high chemical sensitivity. The sensitivity of TERS with atomic force microscopy(AFM) system is mainly determined by the metalized tips. Here, we report a fabrication protocol for AFM-TERS tips that incorporate a copper(Cu) primer film between a gold(Au) layer and a Si AFM tip. They were fabricated by coating the Si tip with a 2 nm Cu layer prior to adding a 20 nm Au layer. For top illumination TERS experiments, these tips exhibited superior TERS performance relative to that observed for tips coated with Au only. Samples included graphene, thiophenol and brilliant cresyl blue. The results may derive from the surface roughness of the tip apex and a Cu/Au synergism of local surface plasmon resonances.Tip-enhanced Raman spectrum（TERS） is a scanning probe technique for acquiring chemical information at high spatial resolution and with high chemical sensitivity. The sensitivity of TERS with atomic force microscopy（AFM） system is mainly determined by the metalized tips. Here, we report a fabrication protocol for AFM-TERS tips that incorporate a copper（Cu） primer film between a gold（Au） layer and a Si AFM tip. They were fabricated by coating the Si tip with a 2 nm Cu layer prior to adding a 20 nm Au layer. For top illumination TERS experiments, these tips exhibited superior TERS performance relative to that observed for tips coated with Au only. Samples included graphene, thiophenol and brilliant cresyl blue. The results may derive from the surface roughness of the tip apex and a Cu/Au synergism of local surface plasmon resonances.

关 键 词：tip enhanced Raman spectrum metalized tip graphene THIOPHENOL brilliant crystal blue 

分 类 号：O657.37[理学—分析化学]