the CAMS Innovation Fund for Medical Sciences(CIFMS)(grant nos.2019-I2M-5-074,2021-I2M-1-026,2021-I2M-3-001,and 2022-I2M-2-002);the National Natural Science Foundation of China(grant nos.81773564,82173678 and 22307052);the Program for Chang-Jiang Scholars and Innovative Research Team in University(grant no.IRT_15R27);the fellowship of China Postdoctoral Science Foundation(grant no.2021M701533);the Gansu Science and Technology Program(grant nos.23JRRA1103,22JR5RA502,and 21JR7RA449).
Late-stage peptide modification showcases a huge potential for the construction of peptide libraries,and the investigation of structure-activity relationships.Herein we report a dimethyl sulfoxide/visible light comedi...
supported by the National Key Basic Research Program of China(No.2021YFA1202803);the National Natural Science Foundation of China(No.22072032);the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB36000000)。
Nanozymes,as a novel form of enzyme mimics,have garnered considerable interest.Despite overcoming the main disadvantages of their natural analogs,they still face challenges such as restricted mimic types and low subst...
supported by the National Natural Science Foundation of China(Nos.22077099 and 22171223);the Technology Innovation Leading Program of Shaanxi(No.2020TG-031);the Innovation Capability Support Program of Shaanxi(Nos.2023-CXTD-75 and 2022KJXX-32);the Natural Science Basic Research Program of Shaanxi(No.2023-JC-YB-141);Young Talent Fund of Association for Science and Technology in Shaanxi,China(No.SWYY202206);the Natural Science Basic Research Plan in Shaanxi Province of China(Nos.2022JQ-151 and 2022JQ-125).
Thiophenol(PhSH)is an important raw material for organic synthesis,while its high toxicity to organisms makes it an environmental pollutant.Therefore,it is crucial to accurately detect PhSH and explore its metabolic p...
supported by Natural Science Foundation of Zhejiang Province(LQ21C200002);Zhejiang Provincial Key Research and Development Program(2021CO2062,2022C02028);Key Research and Development Program of Ningbo(2021Z056,2022S163)
Herein,the 2,4-dinitrophenyl functional group acting as the thiophenol reactive site was introduced into a carbazole-chalcone fluorophore to synthesize probe-CCF2,which could result in a remarkable increase in fluores...
supported by the National Natural Science Foundation of China(No.22073073);the Startup Foundation of Northwest University;The Double First-Class University Construction Project of Northwest University。
A new diabatic potential energy matrix(PEM)of the coupled~^(1)ππ^(*)and~1πσ*states for the~1πσ*-mediated photodissociation of thiophenol was constructed using a neural network(NN)approach.The diabatization of th...
supported by the National Natural Science Foundation of China(No.22073073);Changjian Xie thanks the Startup Foundation of Northwest University;The Double First-class University Construction Project of Northwest University is acknowledged。
Three-dimensional(3D)diabatic potential energy surfaces(PESs)of thiophenol involving the S0,and coupled 1ππ^(*) and 1πσ^(*) states were constructed by a neural network approach.Specifically,the diabatization of th...
A novel molecular probe system(NapTpa-dnbs)was prepared based on the chromophore napthalimide fused triphenylamine unit.NapTpa-dnbs was tuned to absorb a large fraction of UV and near-infrared radiation.The turn-on fl...
The synthesis of a series of unsaturated 4-methylene-1,3-dioxolanes has been realized and the addition of thiophenol to the synthesized compounds in the presence of radical initiators has been carried out. It has been...
This work was financially supported by the National Natural Science Foundation of China (21421005, 21422601, 21576037 and U1608222).
Thiophenol has been listed as one of the main sources of pollution. Sensitive probes for thiophenol are very significant. Herein, a BODIPY-based fluorescent probe, named BDP, for poisonous thiophenol detection has bee...
supported by the National Basic Research Program of China(2011YQ03012415,2011CB808700);the National Natural Science Foundation of China(21127901,233010,21121063);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12020100)
Tip-enhanced Raman spectrum(TERS) is a scanning probe technique for acquiring chemical information at high spatial resolution and with high chemical sensitivity. The sensitivity of TERS with atomic force microscopy(AF...