Ruthenium Trichloride Catalyzed Highly Efficient Deoximation of Oximes to the Carbonyl Compounds and Nitriles without Acceptors  

作　　者：Yuxiao Liu Na Yang Changhu Chu Renhua Liu 

机构地区：[1]School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China

出　　处：《Chinese Journal of Chemistry》2015年第9期1011-1014,共4页中国化学（英文版）

基　　金：Financial support from the National Natural Science Foundation of China （No. 21072055） and the National High Technology Research and Development Program of China （863 Program） （No. 2008AA06Z306）.

摘　　要：An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles with excellent isolated yields.An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles with excellent isolated yields.

关 键 词：DEOXIMATION ruthenium trichloride hydrolysis acceptor-free 

分 类 号：O623.5[理学—有机化学] TQ113.247[理学—化学]