DEOXIMATION

作品数:13被引量:16H指数:3
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相关领域:理学更多>>
相关期刊:《有机化学》《Science Bulletin》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
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A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene
《Chinese Chemical Letters》2025年第3期290-293,共4页Xiaoxue Li Hongwei Zhou Rongrong Qian Xu Zhang Lei Yu 
the Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);the Cooperation Project of Yangzhou City with Yangzhou University(No.YZ2023209);Jiaxing Key Laboratory for Creation of Animal Models&Synthesis of Lead Compounds of New Drug(No.jxsz21006);the Priority Academic Program Development of Jiangsu Higher Education Institutions for support。
The synergistic effect of Se with Fe can enhance the catalytic activities of the system for oxidation reactions.Based on this principle,a series of Se/Fe materials have been invented to develop the heterogeneous catal...
关键词:SELENIUM Anthracene POLYENE OXIDATION DEOXIMATION 
Mo@PANI-catalyzed oxidative deoximation reaction被引量:1
《Chinese Chemical Letters》2024年第2期407-410,共4页Yiyang Zhang Wen Li Zuofeng Hu Xiaobi Jing Lei Yu 
Priority Academic Program Development of Jiangsu Higher Education Institutions for support;financially supported by the fund of the joint-laboratory of Shanghai Dingya Pharmaceutical Chemical Technology Co.,Ltd.with Yangzhou University(No.2022-2027).
Deoximation is an important transformation in synthetic industry.It can be employed in protection,characterization and purification of the carbonyls,and in the synthesis of ketones from non-carbonyl molecules.In the f...
关键词:MOLYBDENUM POLYANILINE Oxidation DEOXIMATION CARBONYL 
Polyaniline-supported tungsten-catalyzed oxidative deoximation reaction with high catalyst turnover number被引量:4
《Chinese Chemical Letters》2023年第1期347-350,共4页Wen Li Feng Wang Yaocheng Shi Lei Yu 
Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);Natural Science Foundation of Jiangsu Province(No.BK20181449);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for support。
Polyaniline-supported tungsten(W@PANI)was easily prepared by immersing polyaniline(PANI)in the aqueous solution of Na2WO4.It was found to be an efficient catalyst for oxidative deoximation reaction,the very important ...
关键词:DEOXIMATION CARBONYL TUNGSTEN Free radical reaction Oxidation 
Organotellurium-catalyzed oxidative deoximation reactions using visible-light as the precise driving energy被引量:2
《Chinese Chemical Letters》2021年第3期1029-1032,共4页Xin Deng Rongrong Qian Hongwei Zhou Lei Yu 
the Natural Science Foundation of Jiangsu Province(No.BK20181449);Natural Science Foundation of Zhejiang Province(No.LY19B020004);Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for financial support。
Irradiated by visible light,the recyclable(PhTe)2-catalyzed oxidative deoximation reaction could occur under mild conditions.In comparison with the thermo reaction,the method employed reduced catalyst loading(1 mol%vs...
关键词:Photocatalysis TELLURIUM DEOXIMATION Sustainable energy KETONE 
Organotellurium catalysis-enabled utilization of molecular oxygen as oxidant for oxidative deoximation reactions under solvent-free conditions被引量:3
《Science Bulletin》2019年第17期1280-1284,共5页Xin Deng Hongen Cao Chao Chen Hongwei Zhou Lei Yu 
financially supported by the National Key Research and Development Program of China (2018YFD0200100);Natural Science Foundation of Jiangsu Province (BK20181449);Zhejiang Provincial Natural Science Foundation (LY19B020004);Jiangsu Provincial Six Talent Peaks Project (XCL-090);Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Catalyzed by commercially available(PhTe)2, molecular oxygen could be utilized as the mild, cheap and safe oxidant for oxidative deoximation reactions under solvent-free conditions. As the first report on organotellur...
关键词:CHALCOGEN ORGANOTELLURIUM catalysis AEROBIC oxidation DEOXIMATION Free radical TELLURIUM 
Recent advances on deoximation: From stoichiometric reaction to catalytic reaction被引量:5
《Chinese Chemical Letters》2019年第5期937-941,共5页Yinghao Zheng Aiqiong Wu Yangyang Ke Hongen Cao Lei Yu 
supported by National Key Research and Development Program of China (No. 2018YFD0200100);Natural Science Foundation of Guangling College (Key Project: No. ZKZD17005; major special project: No. ZKZZ18001);Natural Science Foundation of Jiangsu Province (No. BK20181449);Jiangsu Provincial Six Talent Peaks Project (No. XCL-090);Opening Foundation of the Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University (No. 2016GDGP0104);Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Deoximation reaction is one of the most important transformations in organic synthesis and for fine chemical production.Since oximes are easily synthesized from carbonyl compounds and are stable compounds,this reactio...
关键词:DEOXIMATION Oxidation Green CHEMISTRY OXIME CARBONYL Selective REACTION 
Ruthenium Trichloride Catalyzed Highly Efficient Deoximation of Oximes to the Carbonyl Compounds and Nitriles without Acceptors被引量:1
《Chinese Journal of Chemistry》2015年第9期1011-1014,共4页Yuxiao Liu Na Yang Changhu Chu Renhua Liu 
Financial support from the National Natural Science Foundation of China (No. 21072055) and the National High Technology Research and Development Program of China (863 Program) (No. 2008AA06Z306).
An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles ...
关键词:DEOXIMATION ruthenium trichloride hydrolysis acceptor-free 
Deoximation Reaction in Room Temperature Ionic Liquids under Mild Conditions
《Chinese Journal of Chemistry》2011年第9期1846-1850,共5页Zhang, Xiaoxia Lu, Bin Wang, Xiaoguang Zhao, Jingxiang Cai, Qinghai 
Project supported by the Natural Science Foundation of Heilongjiang Province, China (Nos. ZD200820-01 and B200814).
Deoximation in metal chloride ionic liquids based on 1-alkyl-3-methylimidazolium and triethylene ammonium cations, such as AmimBr(Cl)-MClx (A=ethyl, butyl, benzyl; M=Al, Fe, Cu, Sn and Zn; x=2, 3) and Et3NHCl-FeCl...
关键词:DEOXIMATION OXIME ionic liquids SOLVENT-FREE 
A novel catalytic method for the regeneration of carbonyl compounds from oximes using aluminum nitrate and NaBr as catalyst被引量:1
《Chinese Chemical Letters》2010年第9期1083-1086,共4页Arash Ghorbani-Choghamarani Javad Zeinivand 
support for this work by the research facilities of Ilam University
A wide variety of aldoximes and ketoximes were regenerated to corresponding carbonyl compounds with Al(NO3)3·9H2O in presence of catalytic amounts of NaBr in CH2Cl2 at room temperature.
关键词:DEOXIMATION Aluminum nitrate[Al(NO3)3·9H2O] NABR OXIMES 
A green and efficient deoximation using H_2O_2 catalyzed by montmorillonite-K10 supported CoCl_2被引量:1
《Chinese Chemical Letters》2007年第12期1451-1454,共4页Ali Ezabadi Gholam Reza Najafi Mohammed M.Hashemi 
Oximes were oxidized to the corresponding carbonyl compounds in good to high yields by environmentally friendly and green oxidant, H202 catalyzed by montmorillonite K-10 supported cobalt(Ⅱ) chloride.
关键词:Green deoximation system Hydrogen peroxide Montmorillonite K-IO Cobalt(II) chloride 
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