the Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);the Cooperation Project of Yangzhou City with Yangzhou University(No.YZ2023209);Jiaxing Key Laboratory for Creation of Animal Models&Synthesis of Lead Compounds of New Drug(No.jxsz21006);the Priority Academic Program Development of Jiangsu Higher Education Institutions for support。
The synergistic effect of Se with Fe can enhance the catalytic activities of the system for oxidation reactions.Based on this principle,a series of Se/Fe materials have been invented to develop the heterogeneous catal...
Priority Academic Program Development of Jiangsu Higher Education Institutions for support;financially supported by the fund of the joint-laboratory of Shanghai Dingya Pharmaceutical Chemical Technology Co.,Ltd.with Yangzhou University(No.2022-2027).
Deoximation is an important transformation in synthetic industry.It can be employed in protection,characterization and purification of the carbonyls,and in the synthesis of ketones from non-carbonyl molecules.In the f...
Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);Natural Science Foundation of Jiangsu Province(No.BK20181449);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for support。
Polyaniline-supported tungsten(W@PANI)was easily prepared by immersing polyaniline(PANI)in the aqueous solution of Na2WO4.It was found to be an efficient catalyst for oxidative deoximation reaction,the very important ...
the Natural Science Foundation of Jiangsu Province(No.BK20181449);Natural Science Foundation of Zhejiang Province(No.LY19B020004);Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for financial support。
Irradiated by visible light,the recyclable(PhTe)2-catalyzed oxidative deoximation reaction could occur under mild conditions.In comparison with the thermo reaction,the method employed reduced catalyst loading(1 mol%vs...
financially supported by the National Key Research and Development Program of China (2018YFD0200100);Natural Science Foundation of Jiangsu Province (BK20181449);Zhejiang Provincial Natural Science Foundation (LY19B020004);Jiangsu Provincial Six Talent Peaks Project (XCL-090);Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Catalyzed by commercially available(PhTe)2, molecular oxygen could be utilized as the mild, cheap and safe oxidant for oxidative deoximation reactions under solvent-free conditions. As the first report on organotellur...
supported by National Key Research and Development Program of China (No. 2018YFD0200100);Natural Science Foundation of Guangling College (Key Project: No. ZKZD17005; major special project: No. ZKZZ18001);Natural Science Foundation of Jiangsu Province (No. BK20181449);Jiangsu Provincial Six Talent Peaks Project (No. XCL-090);Opening Foundation of the Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University (No. 2016GDGP0104);Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Deoximation reaction is one of the most important transformations in organic synthesis and for fine chemical production.Since oximes are easily synthesized from carbonyl compounds and are stable compounds,this reactio...
Financial support from the National Natural Science Foundation of China (No. 21072055) and the National High Technology Research and Development Program of China (863 Program) (No. 2008AA06Z306).
An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles ...
Project supported by the Natural Science Foundation of Heilongjiang Province, China (Nos. ZD200820-01 and B200814).
Deoximation in metal chloride ionic liquids based on 1-alkyl-3-methylimidazolium and triethylene ammonium cations, such as AmimBr(Cl)-MClx (A=ethyl, butyl, benzyl; M=Al, Fe, Cu, Sn and Zn; x=2, 3) and Et3NHCl-FeCl...
support for this work by the research facilities of Ilam University
A wide variety of aldoximes and ketoximes were regenerated to corresponding carbonyl compounds with Al(NO3)3·9H2O in presence of catalytic amounts of NaBr in CH2Cl2 at room temperature.
Oximes were oxidized to the corresponding carbonyl compounds in good to high yields by environmentally friendly and green oxidant, H202 catalyzed by montmorillonite K-10 supported cobalt(Ⅱ) chloride.