Co-Mo/USY催化剂的制备及煤焦油加氢裂化性能研究  

PREPARATION AND COAL TAR HYDROCRACKING PERFORMANCE OF Co-Mo/USY CATALYSTS

作　　者：高歌[1] 王志永[1] 周蓉[1] 陆江银[1] 

机构地区：[1]新疆大学石油与天然气精细化工教育部重点实验室,乌鲁木齐830046

出　　处：《石油炼制与化工》2015年第11期56-61,共6页Petroleum Processing and Petrochemicals

基　　金：国家自然科学基金资助项目(21163019)

摘　　要：以USY型分子筛为载体,通过浸渍法制备了Co-Mo/USY催化剂,采用XRD,NH3-TPD,H2-TPR等手段对催化剂进行表征,并用硫代硫酸铵对催化剂进行器外预硫化,在连续固定床反应器上考察了不同Mo负载量催化剂对煤焦油加氢裂化性能的影响。结果表明,催化剂的最佳Mo负载量(w)为12%,在反应温度385℃、压力9 MPa、质量空速0.6h-1、氢油体积比1 000∶1的条件下,煤焦油加氢裂化的轻质油收率为86%。CoMo/USY hydrocraeking catalysts were prepared using USY molecular sieve as supportby using impregnation method and characterized by XRD, NH3-TPD, H2-TPR. （NH4）2S2O3 was used as a presulfidation agent. The performance of coal tar hydrocracking of catalysts prepared with different Mo loading was investigated by orthogonal test in a continuous flow fixed-bed reactor. The results indicate that the catalyst with 12% Mo is the best. The yield of fuel oil reached 86% under the reaction conditions of a temperature of 385 ℃, a pressure of 9 MPa, a WHSV of 0.6 h^-1 , and a H2/oil ratio of 1 000.

关 键 词：加氢裂化 USY分子筛 催化剂 煤焦油 

分 类 号：TE624.9[石油与天然气工程—油气加工工程]