含氟杀虫剂类农药的残留检测分析研究进展  

Research Progress of Analytical and Detection Methods of Fluorine-containing Pesticides Residues

作　　者：王建芬 丁双阳[2] 王晓琳[3] 

机构地区：[1]北京市延庆县畜牧技术推广站,北京102100 [2]中国农业大学动物医学院,北京100129 [3]河南牧业经济学院,郑州450046

出　　处：《中国农学通报》2016年第2期68-72,共5页Chinese Agricultural Science Bulletin

基　　金：农业部公益性行业(农业)科研专项经费项目"食品质量安全‘主动’控制技术"(201203069-2);奶牛产业技术体系北京市创新团队项目

摘　　要：由于氟原子所具有的特殊功效,近几十年来含氟类农药发展迅速。含氟杀虫剂主要包括拟除虫菊酯和苯甲酰脲中的含氟品种,以及氟虫腈、溴虫腈、茚虫威等杂环类化合物。本研究对含氟杀虫剂类农药的残留分析方法进行了综述,包括样品提取技术、净化技术及检测技术。样品净化技术包括固相萃取和液-液萃取,检测技术主要有气象色谱法、高效液相色谱法、气相色谱-质谱联用(GC-MS)和高效液相色谱-质谱联用(HPLC-MS)。最后从动物性食品安全的角度提出建议。Because of the special function of fluorine atom for organism, fluorine-containing pesticide has beendeveloped quickly in recent decades. The major classes of fluorine- containing pesticides are pyrethroid,benzoylurea and heterocyclic compounds which include fipronil, chlorfenapyr, indoxacarb, etc. In this study,the development of residue analytical methods including extraction, purification and detection techniques offluorine- containing pesticide was described in detail. The purification techniques included solid- phaseextraction and liquid- liquid extraction, the detection techniques included gas chromatography（GC）, highperformance liquid chromatography（HPLC）, GC- MS and HPLC- MS. Finally suggestions were put forwardfrom the aspect of animal derived food safety.

关 键 词：含氟杀虫剂 残留 样品前处理 仪器分析 

分 类 号：S859.84[农业科学—临床兽医学]