电化学法制备石墨烯及其复合材料  

Electrochemical Syntheses of Graphene and Its Composites

作　　者：赵波[1,2] 姜莉[1] 袁铭辉[3] 符显珠[1] 孙蓉[1] 汪正平[4] 

机构地区：[1]中国科学院深圳先进技术研究院,深圳市高密度电子封装材料与器件重点实验室,广东深圳518055 [2]中国科学院大学深圳先进技术学院,北京100049 [3]香港科技大学机械工程学院,中国香港999077 [4]佐治亚理工学院材料科学与工程系,美国亚特兰大30332

出　　处：《电化学》2016年第1期1-19,共19页Journal of Electrochemistry

基　　金：国家自然科学基金项目(No.21203236);广东省引进创新科研团队计划项目(No.2011D052,No.KYPT20121228160843692);深圳市高密度电子封装材料与器件重点实验室项目(No.ZDSYS20140509174237196);深圳市孔雀计划项目(No.KQCX2015033117354154)资助

摘　　要：石墨烯是一种具有优异物理和化学性质的新型二维碳纳米材料,大规模低成本制备高品质石墨烯的方法是其能够得到广泛实际应用的重要前提.电化学方法可以快捷、绿色无污染、批量制备高质量的石墨烯及其复合材料.本综述在对石墨烯各种制备方法进行简要比较之后,对近年来石墨烯、石墨烯/无机纳米复合材料、石墨烯/聚合物复合材料以及类石墨烯材料的电化学法制备进展进行介绍并作了展望.Graphene is a kind of ideal two-dimensional flat carbon nanomaterials possessing unique chemical and physical properties. The attractive potential applications must be based on the high quality mass production of graphene. However, it remains a huge challenge. An electrochemical approach is a fast, environmental friendly and easy-operating method. Single-or multi-layered graphene flakes can be readily produced in short periods of time. In this review, the structures, properties and preparation methods of graphene are first introduced. Accordingly, the electrochemical approaches used for the productions of graphene flakes, graphene/inorganic nanocomposites, graphene/polymer composites and graphene analogues are highlighted. Finally, challenges and opportunities are briefly outlined on the graphene flakes and their composites synthesized by electrochemical methods.

关 键 词：石墨烯 石墨烯复合材料 电化学剥离 电化学氧化 电化学还原 

分 类 号：TQ127.11[化学工程—无机化工] TB33[一般工业技术—材料科学与工程]