1,1′-Binaphthyl-2,2′-diamine Dihydrochloride：an Efficient Ligand for the N-Arylation of Imidazole with Aryl/heteroaryl Halides Catalyzed by CuI  

作　　者：SHEN Guodong ZHAO Lingyu BAO Weiliang 

机构地区：[1]School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China [2]Department of Chemistry, Xi Xi Campus, Zhejiang University, Hangzhou 310028, P. R. China

出　　处：《Chemical Research in Chinese Universities》2016年第6期947-951,共5页高等学校化学研究（英文版）

摘　　要：Employing 1,1′-binaphthyl-2,2′-diamine（BINAM） dihydrochloride as an efficient and commerciallyavailable ligand, relatively mild and highly efficient copper-catalyzed coupling reactions of imidazole with aryl andheteroaryl halides have been developed. Various N-arylimidazoles could be synthesized in moderate to excellentyields.

关 键 词：COPPER-CATALYZED N-ARYLATION N-Arylimidazole Ullmarm-type coupling 

分 类 号：O[理学]