supported by the National Key R&D Program of China(No.2023YFA1507902);the National Natural Science Foundation of China(Nos.21721004 and 21878288);the science and technology bureau of Dalian city(No.2021RT04);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB17020100).
N-participated lignin depolymerization is of great importance for the transformation of waste lignin into value-added chemicals.The vast majority of developed strategies employ organic amines as nitrogen source,and co...
An efficient copper-catalyzed regioselective acyloxy-trifluoromethylation of allenamides using Togni'sⅡreagent as the source of both the trifluoromethyl and acyloxy moieties was developed to create a workable route t...
the funding of the National Natural Science Foundation of China(22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(KFJJ2022013);Anhui Provincial Major Science and Technology Project(2022e03020005).
Arylidenecyclopropanes(ACPs)are highly strained substrates that can be readily utilized for diverse transformations.This study showcases the outcomes of copper-catalyzed ring-opening hydrosilylation and hydroboration ...
supported by the Natural Science Foundation of Jilin Province(20210101134JC);the National Natural Science Foundation of China(22171042,21831002,22193012);the Fundamental Research Funds for the Central Universities.
Alicyclic nitrogen heterocycles,such as enantioenriched polycyclic fused[1,2-a]indoline derivatives,are widespread in natural products,agrochemicals and pharmaceutical agents.Existing methods predominantly rely on the...
Synthetic electrochemistry has been selected as one of the Top Ten Emerging Technologies in Chemistry in 2023 by International Union of Pure and Applied Chemistry(IUPAC)^([1]).It has emerged as a sustainable platform ...
Financial supports were obtained from the National Natural Science Foundation of China(NSFC,grant nos.22025103,22331006,92256301,22371112,and 22101122);the National Key R&D Program of China(grant nos.2021YFF0701604 and 2021YFF0701704);Guangdong Major Project of Basic and Applied Basic Research,China(grant no.2023B0303000020);Guangdong Basic and Applied Basic Research Foundation,China(grant no.2023A1515140088);Shenzhen Science and Technology Program,China(grant nos.JCYJ20220818100600001,JCYJ202205300115409020,and 20220814231741002);the Shenzhen Key Laboratory of Cross-Coupling Reactions,China(grant no.ZDSYS20220328104200001);Dongguan Key Laboratory of Interdisciplinary Science for Advanced Materials and Large-Scale Scientific Facilities,China(grant no.2023KSYS014);Also,the New Cornerstone Science Foundation through the XPLORER PRIZE is gratefully acknowledged.
The asymmetric radical carboamination of 1,1-disubstituted alkenes from readily available alkyl halides and arylamines provides expedient access to valueadded chiralα-tertiary N-arylamines but has been less recognize...
the National Natural Science Foundation of China(Nos.21971001 and 21702001)for financial support.
A copper-catalyzed three-component reaction of diazo compounds,nitriles,and azodicarboxylates to construct 2,3-dihydro-1,2,4-triazoles is reported.Key to the success is the utilization of azodicarboxylates to trap the...
supported by the National Natural Science Foundation of China(22188101);Sichuan Science and Technology Program(2021YJ0561)。
An efficient catalytic asymmetric dearomatizing amination of 2-naphthols and phenols catalyzed by N,N′-dioxide-copper(I)complex as a chiral catalyst was presented.A variety of optically activeβ-naphthalenone compoun...
Financial support from the National Natural Science Foundation of China(Nos.21971201,22171220);the Fundamental Research Funds of the Central Universities(No.xtr072022003)。
A photoinduced copper-catalyzed alkoxyl triggered C-C bond cleavage/aminocarbonylation cascade is presented.Through adjusting the structure of alkoxyl radical precursors,functionalized lactones and ketoamides were syn...
supported by the National Key R&D Program of China(2021YFA1501100);the National Natural Science Foundation of China(22005007);the New Cornerstone Science Foundation,and Liaoning Binhai Laboratory Project(LBLF-202306);the Tencent Foundation through the XPLORER PRIZE.
A hydrogen storage system was developed via heterogeneous catalysis,employing the dehydrogenative coupling of methanol and N,N′-dimethylethylenediamine to efficiently produce high-purity H_(2).In this process,the Cu/...