Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine  

作　　者：Danyang Cheng Shixiang Yu Meng Wang Ding Ma 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,New Cornerstone Science Laboratory,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China

出　　处：《Precision Chemistry》2024年第4期138-142,共5页精准化学（英文）

基　　金：supported by the National Key R&D Program of China(2021YFA1501100);the National Natural Science Foundation of China(22005007);the New Cornerstone Science Foundation,and Liaoning Binhai Laboratory Project(LBLF-202306);the Tencent Foundation through the XPLORER PRIZE.

摘　　要：A hydrogen storage system was developed via heterogeneous catalysis,employing the dehydrogenative coupling of methanol and N,N′-dimethylethylenediamine to efficiently produce high-purity H_(2).In this process,the Cu/ZnO/Al_(2)O_(3) catalyst displayed superior activity in hydrogen production,with Cu+identified as the major active site through comprehensive characterization.

关 键 词：methanol reforming hydrogen release AMINOCARBONYLATION dehydrogenative coupling Cu/ZnO/Al_(2)O_(3)catalyst 

分 类 号：O64[理学—物理化学]