两种四足席夫碱对环境水样中Fe(Ⅲ)离子的比色识别（英文）  

Two Tetrapodal Schiff Bases Acting as Colorimetric Sensors for Iron in Environmental Water Samples

作　　者：王若[1] 江光奇[2,1] 

机构地区：[1]贵州大学化学与化工学院,贵阳50025 [2]贵州大学精细化工研究开发中心绿色农药和农业生物工程教育部重点实验室,贵阳550025

出　　处：《无机化学学报》2017年第5期881-889,共9页Chinese Journal of Inorganic Chemistry

基　　金：financial support from the Foundation of Guizhou Province, China (Grant No.[2014] 7619);the Teaching Reform and Research Project of the Guizhou University, China (Grant No.JG 2013014); the science and technology innovation foundation of the Guizhou University (Grant No.2016009); the opening foundation of the Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University (Grant No. 2016GDGP0102)~~

摘　　要：使用季戊四胺与水杨醛、邻香兰素缩合反应得到了两种席夫碱化合物1和2。化合物1和2均可用于不同水样Fe(Ⅱ)和Fe(Ⅲ)离子的比色识别。通过光谱滴定及液质谱联用等方法研究了化合物1和2与Fe(Ⅲ)的识别作用,化合物1和2与Fe(Ⅲ)离子的配位比为1∶1,对Fe(Ⅲ)铁离子的检出限分别为0.19和0.21μmol·L^(-1),低于世界卫生组织饮用水检出标准(5μmol·L^(-1)),具有一定的实用价值。Two colorimetric sensors, derived from pentaerythrityltetramine and salicylaldehyde （1） or o-vanillin （2）, had been synthesized. Both sensors showed selective colorimetric sensing ability for Fe（Ⅱ） and Fe （Ⅲ） by changing color from light yellow to either orange or purple when immersed in water samples, The sensors coordinated to Fe（Ⅲ） with 1：1 stoichiometry, as has been confirmed from the results of LC-MS spectrometry and UV-Vis spectrum titration. The detection limits of sensors 1 （0.19 μmol.L-1） and 2 （0.21 μmol.L-1） are lower than the WHO guideline （5 μmol. L-1） in drinking water.

关 键 词：席夫碱 比色传感器 铁离子 

分 类 号：O614.811[理学—无机化学]