蛋白石型光子晶体红外隐身材料的制备  

Preparation of opal photonic crystal infrared stealth materials

作　　者：张连超[1] 邱丽莉[1] 芦薇[1] 于颖杰[1] 孟子晖[1] 王树山[2] 薛敏[1] 刘文芳[1] 

机构地区：[1]北京理工大学化学与化工学院,北京100081 [2]北京理工大学机电学院,北京100081

出　　处：《物理学报》2017年第8期134-140,共7页Acta Physica Sinica

基　　金：国家自然科学基金(批准号:21375009;U153010105);北京理工大学科技创新计划基础研究基金(批准号:20151042004)资助的课题~~

摘　　要：基于光子晶体的红外隐身材料,主要采取一维层层堆叠结构和三维木堆结构等来实现对红外波段电磁波辐射性能的调控.本文报道了一种操作简易、成本低廉的光子晶体红外隐身材料制备方法.通过优化的垂直沉积法,微米级SiO_2胶体微球自组装成高质量的蛋白石型光子晶体结构.对SiO_2胶体微球进行优选,成功制备了禁带位于2.8—3.5μm,8.0—10.0μm的SiO_2胶体晶体蛋白石型光子晶体材料.该材料可改变目标相应波段的红外辐射特征,具有目标红外波段的隐身效果.With the development of infrared detection technology,the survival of military target is now under serious threat.Therefore,new infrared stealth technologies and materials are now in an urgent demand.The photonic crystal（PhC）possesses regularly repeating structure which results in band-gap and diffraction satisfying Bragg＇s law of diffraction.The PhC presents unique optical properties and functionality.The PhC with band-gap located in visible band is used widely as biosensor,chemical sensor,optical filter,reflector,modulator,metasurface and solar cell.The PhC with bandgap located in infrared band can be used to control the propagations of the electromagnetic waves of infrared band,and could be used as a promising material in the infrared stealth technology.Photonic structure used to tune the infrared radiation usually has a one-dimensional layer-by-layer stack or threedimensional wood pile structure.However,the poor flexibility,low strength,small area coverage,complicated fabrication process and high cost can prevent this new infrared stealth technology from being applied and developed.In this report,a simple and cost-effective method of preparing the opal PhC materials is proposed,and this infrared stealth material forbids electromagnetic waves of infrared band to propagate on account of band-gap.In this paper,opal PhCs materials with high quality are assembled from SiO2 colloidal microspheres with micrometer size by using optimized vertical deposition method.We calculate the relation between the diameter of SiO2 colloidal microsphere and the frequency of opal PhCs band-gap in theory and verified in experiment,which operates in the working band of infrared detector.The results show that the diameters of SiO2 colloidal microspheres should be 1.33-2.22 μm and 3.56-5.33 μm.A series of monodispersed micrometer SiO2 colloidal microspheres is prepared by the modified Stober method,and bigger microspheres are prepared by using the seeded polymerization method.Then,we choose the diameters of 1.5 μm and 4.3 μm

关 键 词：光子禁带 胶体阵列 垂直沉积法 红外隐身 

分 类 号：O734[理学—晶体学]