气相色谱-三重四极杆质谱分析人参炮制品中的挥发性成分  

Analysis of Volatile Components in Processed Ginseng by GC-MS/MS

作　　者：王微[1] 郑飞[1] 葛岩[1] 乔梦丹 越皓[1] 刘淑莹[1] WANG Wei ZHENG Fei GE Yan QIAO Mengdan YUE Hao LIU Shuying(Jilin Ginseng Academy, Changchun University of Chinese Medicine, Changchun 130117, China)

机构地区：[1]长春中医药大学,吉林省人参科学研究院,长春130117

出　　处：《应用化学》2017年第8期965-970,共6页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金资助项目(3140040275)~~

摘　　要：人参炮制的化学成分变化研究主要集中在皂苷和糖类,本文首次从挥发性成分角度阐释了人参不同炮制品的物质基础。利用气相色谱-质谱联用(GC-MS/MS)方法,对鲜参、生晒参和红参中挥发性成分及其衍生规律进行研究。采用TG-5SILMS非极性气相色谱柱,以He为载气,通过NIST MS Spectral Database对挥发性成分进行检测并鉴定。鲜参、生晒参、红参中分别检出30、33和34种挥发性成分,其中生晒参中(-)-斯巴醇含量为鲜参含量的31.98倍,辛醛等8种挥发性成分为鲜参中含量的3倍以上,红参中有环癸等10种挥发性成分为鲜参中含量的3倍以上。生晒参和红参中各有4种挥发性成分在鲜参中未检出。The research of chemical changes in ginseng processing has been focusing on saponins and sugars.In this paper, volatile components in ginseng were studied for the first time, which provide a substance basis for different processed ginseng. The volatile components and their derivative paths of fresh ginseng, sun-dry ginseng and red ginseng were studied by gas chromatography-mass spectrometry （GC-MS/MS）. The volatile components were detected and analyzed through the NIST MS Spectral Database. fresh ginseng, sun-dry ginseng and red alcohol in sun-dry ginseng is 31.98 times using TG-SSILMS nonpolar GC column, with He as the carrier gas Thirty, thirty-three and thirty-four species of volatile compounds in ginseng were detected, respectively. The content of （-）-spartak higher than that in the fresh ginseng, while the levels of eight volatile components such as octanal in sun-dry ginseng is three times higher than those in the fresh ginseng. The contents of ten volatile components such as cyclodecanone in red ginseng are 3 times higher than those in the fresh ginseng. Four volatile compounds in sun-dry ginseng and in red ginseng are not detected in fresh ginseng.

关 键 词：气相色谱-三重四极杆质谱 鲜参 生晒参 红参 挥发性成分 

分 类 号：O657[理学—分析化学]