煤电化学脱硫试验研究  

Coal Chemical Desulfurization Experiment Research

作　　者：张鸿波[1] 孙瑞[1] 丁淑芳[1] 胡秉双 李悦 ZHANG Hong- bo SUN Rui DING Shu- fang HU Bing- shuang LI Yue(School of Mining Engineering, Heilongjiang University of Science ＆ Technology, Harbin 150022, China Jixi Yatai Coal Limited, Jixi 158110, Heilongjiang Province, China Hegang Teachers College, Hegang 154000, Heilongjiang Province, China.)

机构地区：[1]黑龙江科技大学矿业工程学院,哈尔滨150022 [2]鸡西亚泰选煤有限公司,黑龙江鸡西158110 [3]鹤岗师范高等专科学校,黑龙江鹤岗154000

出　　处：《应用能源技术》2017年第7期33-35,共3页Applied Energy Technology

基　　金：基金项目:黑龙江科技大学青年才俊(Q20100205)

摘　　要：为了研究电解前后煤中硫分的变化,对含硫量为3.08%的高硫煤样进行电化学脱硫处理。用氢氧化钠溶液浸泡煤样后进行电化学处理,对电解后煤样进行洗涤、过滤、烘干。采用X射线荧光技术、X-射线衍射技术和红外光谱仪等检测手段,分析电解后煤样元素和有机基团的变化。实验结果表明:电解后煤中硫铁矿、双硫键明显较少,说明电解反应可以脱除煤中大部分硫。In order to study the changes of sulfur content in coal before and after electrolytic,electrochemical desulfurization mechanism,this experiment adopts the total sulfur content up to 3.08% of the high sulfur coal sample,sulfur content are mainly pyrite sulfur,organic sulfur. First of all,with a sodium hydroxide solution soak in electrolysis after coal sample,the electrolytic coal sample after washing, filtering and drying. Then, by X ray fluorescence technology, X-ray diffraction technology and infrared spectrometer,qualitative and quantitative analysis of coal samples after electrolytic elements,the change of the organic groups in coal. The experimental results show that the sulfur in coal has significantly decreased after electrolytic,explain the electrolytic reaction to removal of sulfur in coal.

关 键 词：电化学脱硫 红外光谱 硫铁矿硫 硫酸根 

分 类 号：TQ530.2[化学工程—煤化学工程]