KI Catalyzed Nitrogenation of Aldehydes and Alcohols： Direct Synthesis of Carbamoyl Azides and Ureas  

作　　者：Song Song Peng Feng Miancheng Zou Ning Jiao 

机构地区：[1]State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing 100191, China [2]Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, China

出　　处：《Chinese Journal of Chemistry》2017年第6期845-848,共4页中国化学（英文版）

基　　金：Financial support from National Basic Research Program of China （973 Program） （No. 2015CB856600）, the National Natural Science Foundation of China （Nos. 21325206, 21632001）, National Young Top-notch Talent Support Program, CAS Interdisciplinary Innovation Team, and Peking University Health Science Center （Nos. BMU20150505, BMU20160541） is greatly ap- preciated. We thank Bencong Zhu and Ao Sun in this group for reproducing the results of 2a and 2k.

摘　　要：An efficient KI catalyzed nitrogenation of aldehydes and alcohols for the direct synthesis of carbamoyl azides and ureas via a radical process has been developed. The simple operating procedures, the readily available starting materials including aldehydes, alcohols and amines, as well as the utility of the products all make this strategy very attractive.An efficient KI catalyzed nitrogenation of aldehydes and alcohols for the direct synthesis of carbamoyl azides and ureas via a radical process has been developed. The simple operating procedures, the readily available starting materials including aldehydes, alcohols and amines, as well as the utility of the products all make this strategy very attractive.

关 键 词：NITROGENATION ALDEHYDES carbamoyl azides UREAS KI TBHP 

分 类 号：O643.36[理学—物理化学] TQ225.52[理学—化学]