Synthesis of Substituted Naphtho-Ferrocenes via a Gold（I）- Catalyzed Intramolecular 6-endo-Dig Cyclization  

作　　者：Pei-Chao Zhang Yidong Wang Deyun Qian Wenbo Li Junliang Zhang 

机构地区：[1]Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China [2]State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

出　　处：《Chinese Journal of Chemistry》2017年第6期849-852,共4页中国化学（英文版）

基　　金：We are grateful to the Shanghai Sailing Program （No. 16YF 1402800）, the 973 programs （No. 2015CB856600）, National Natural Science Foundation of China （No. 21425205）, and Shanghai Eastern Scholar Program for financial supports.

摘　　要：A novel series of naphtho-ferrocene derivatives were synthesized in high yields by an efficient gold-catalyzed intramolecular 6-endo-dig cyclization strategy. The salient features of this reaction include easy operation, broad substrate scope, high yields, mild conditions and it works well in wet solvent under air at room temperature.A novel series of naphtho-ferrocene derivatives were synthesized in high yields by an efficient gold-catalyzed intramolecular 6-endo-dig cyclization strategy. The salient features of this reaction include easy operation, broad substrate scope, high yields, mild conditions and it works well in wet solvent under air at room temperature.

关 键 词：gold（I）-catalysis CYCLIZATION HYDROARYLATION PAHs-metallocenes naphtho-ferrocenes 

分 类 号：O643.36[理学—物理化学] TP381[理学—化学]