HYDROARYLATION

作品数:15被引量:15H指数:3
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相关领域:理学更多>>
相关机构:南京大学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Organic Chemistry Frontiers》《Science China Chemistry》《Green Synthesis and Catalysis》更多>>
相关基金:国家自然科学基金高等学校学科创新引智计划福建省自然科学基金更多>>
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Highly selectiveα-C(sp^(3))-H arylation of alkenyl amides via nickel chain-walking catalysis
《Chinese Chemical Letters》2024年第7期271-275,共5页Haoran Shi Jiaxin Wang Yuqin Zhu Hongyang Li Guodong Ju Lanlan Zhang Chao Wang 
supported by the National Natural Science Foundation of China(Nos.21901185 and 22301216);funds provided by Tianjin Normal University。
Herein,we report the migratory hydroarylation of unactivated alkenes with aryl iodides using native and weakly coordinating amide directors under mild conditions.Synergistic coordination of the monodentate directing g...
关键词:Alkenes HYDROARYLATION Chain-walking Regioselective Nickel catalysis 
Polymer-supported chiral palladium-based complexes as efficient heterogeneous catalysts for asymmetric reductive Heck reaction
《Green Synthesis and Catalysis》2024年第2期102-107,共6页Hui Zhang Bing Xu Liejin Zhou Zhan-Ming Zhang Junliang Zhang 
the National Key R&D Program of China(No.2021YFF0701600);NSFC(No.22031004);the Shanghai Municipal Education Commission(No.20212308);China Postdoctoral Science Foundation(No.2022M713667);STCSM(No.23ZR1445600).
Heterogeneous asymmetric catalysis is an important strategy for the industrial production of chiral compounds.Herein,we reported a polymer-bound Xu-Phos-derived palladium catalyst that shows good performance in hetero...
关键词:Heterogeneous catalysis RECOVERABILITY Palladium HYDROARYLATION Asymmetric catalysis 
Thermocatalytic Dehydrogenation-Enabled Arene-Alkane Couplings
《Chinese Journal of Chemistry》2023年第16期1905-1914,共10页Feng Yu Renqing Tao Lan Gan Hao Ni Qi-Kai Kang Guixia Liu Zheng Huang 
the National Key R&D Program of China(2021YFA1501700);the National Natural Science Foundation of China(21825109,21821002,22072178,22293013).
Comprehensive Summary The direct use of non-prefunctionalized arene and alkane as the starting materials to construct Caryl−Calkyl bond is an unfulfilled target and approaches to this challenge rarely surface in metho...
关键词:ALKANES ARENES Dehydrogenative coupling HYDROARYLATION lridium 
Hydroarylation of terminal alkynes with arylboronic acids catalyzed by low loadings of palladium
《Chinese Chemical Letters》2023年第2期165-169,共5页Lei Xu Shiyu Li Qi Zhang Ning Deng Biao Zhang Huajian Xu 
financial support from the National Natural Science Foundation of China (No. 21472033);the National Key R&D Program of China (No. 2018YFB1501604);the Fundamental Research Funds for the Central Universities (No. PA2020GDKC0021)。
The hydroarylation reaction of terminal alkynes with arylboronic acids catalyzed by low(400 ppm) loadings of palladium has been developed. The reaction is broad in scope and high-yielding, even on multigram scale. It ...
关键词:HYDROARYLATION Low loadings Terminal alkyne Deuterium-labeled PALLADIUM 
Nickel-Catalyzed Regio-and Enantioselective Hydroarylation of 1,3-Dienes with Indoles
《CCS Chemistry》2022年第8期2612-2619,共8页Lei Cheng Ming-Ming Li Mao-Lin Li Li-Jun Xiao Jian-Hua Xie Qi-Lin Zhou 
the National Natural Science Foundation of China(nos.21790330 and 91956000)and the“111”Project(no.B06005)of the Ministry of Education of China for financial support.
The regio-and enantioselective functionalization of 1,3-dienes has become a powerful tool for the synthesis of allylic compounds,yet it remains a challenge for aliphatic dienes.Herein,we report a nickel-catalyzed asym...
关键词:nickel catalyst aliphatic diene asymmetric hydroarylation chiral indole derivatives C–C bond formation 
Manganese-Catalyzed Anti-Markovnikov Hydroarylation of Enamides:Modular Synthesis of Arylethylamines
《Chinese Journal of Chemistry》2022年第13期1546-1552,共7页Yjie He Chaoyu Du Jian Han Jie Han Chengjian Zhu Jin Xie 
We gratefully acknowledge the National Natural Science Foundation of China(22122103,22101130,22001116,21971108,21971111,21732003);the National Key Research and Development Program of China(2021YFC2101901);the Fundamental Research Funds for the Central Universities(020514380252);the Natural Science Foundation of Jiangsu Province(Grant No.BK20190006);the Guangdong Basic and Applied Basic Research Foundation(2020A1515110816);the"Innovation&Entrepreneurship Talents Plan"of Jiangsu Province.Nian Li,Chuan-Gang Zhao,Junheng Liu are warmly acknowledged to reproduce experimental procedures for products 3ii,5p and 3a.
The arylethylamine framework is a prevalent motif in a great range of biologically important organic compounds.One intractable task for frontline drug discovery is to find structurally new medicine candidates instead ...
关键词:ALKENES ANTI-MARKOVNIKOV Homogeneous catalysis AMINES Difunctionalization 
Metal-free intramolecular hydroarylation of alkynes
《Organic Chemistry Frontiers》2022年第5期1300-1307,共8页Chaofeng Zhang Songkui Lv Yanru Wang Jingyi Zhang Xiao-Na Wang Junbiao Chang 
We thank the National Natural Science Foundation of China(no.81803406 and U1804283);the Foundation of Henan Educational Committee(19A150009)for financial support.
An efficient metal-free intramolecular hydroarylation reaction of alkynes is described here.A series of aryl and N-group attached alkynes generated the intramolecular hydroarylation products in high yields.
关键词:INTRAMOLECULAR ALKYNES free 
NiH-Catalyzed Reductive Hydrocarbonation of Enol Esters and Ethers被引量:1
《CCS Chemistry》2022年第2期605-615,共11页Xiao-Xu Wang Lu Yu Xi Lu Zhi-Lin Zhang De-Guang Liu Changlin Tian Yao Fu 
the National Natural Science Foundation of China(grant nos.21732006,51821006,21927814,and 51961135104);the Strategic Priority Research Program of CAS(grant nos.XDB20000000 and XDB37040000);the USTC Research Funds of the Double First-Class Initiative(grant no.YD3530002002);the Users with Excellence Program of Hefei Science Center CAS(grant nos.2019HSCUE017 and 2019HSC-UE005).
Chiral dialkyl carbinols and their derivatives are significant synthetic building blocks in organic chemistry and related fields.The development of convenient and efficient methods to access these compounds has long b...
关键词:nickel hydride asymmetric synthesis radical coupling reductive hydroalkylation reductive hydroarylation enol ester enol ether 
Dearomative spirocyclization via visible-light-induced reductive hydroarylation of non-activated arenes
《Chinese Chemical Letters》2022年第1期225-228,共4页Zhuomin Chi Yuzhen Gao Lei Yang Chunlin Zhou Meng Zhang Peiming Cheng Gang Li 
the financial supports from the National Natural Science Foundation of China(Nos.22022111,21871257,21801240);the Natural Science Foundation of Fujian Province(No.2020J02008);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)。
A visible-light-induced spirocyclizative hydroarylation via reductive dearomatization of a series of non activated arenes including 2-phenyl indoles and naphthalene derivatives under mild conditions is de scribed.An i...
关键词:Visible-light-induced Non-activated arene SPIROCYCLIZATION Dearomatization Reductive hydroarylation 
Kinetic Resolution of 2-Substituted 1,2-Dihydroquinolines by Rhodium-Catalyzed Asymmetric Hydroarylation被引量:2
《Chinese Journal of Chemistry》2021年第6期1606-1610,共5页Baohua Cai Qingjing Yang Ling Meng Jun(Joelle)Wang 
the Shenzhen Overseas High-level Talents Innovation Plan of Technical Innovation Project(No.KQJSCX20180319114439973)for financial support.
A highly efficient kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via Rh-catalyzed asymmetric hydroarylation has been described for the first time.A variety of arylboronic acids coupled with 2-subst...
关键词:Kinetic resolution HYDROARYLATION TETRAHYDROQUINOLINE Asymmetric catalysis Transition metal 
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