The efficient hydrogenolysis of esters to alkanes is the key protocol for producing advanced biofuels from renewable plant oils or fats.Due to the low reactivity of the carbonyl group in esters,a high reaction tempera...
The heavy consumption of non-renewable fossil feedstocks has induced several vital problems such as global warming and energy crises.Biomass,particularly lignin,is a promising renewable resource to substitute fossil f...
supported by the China Postdoctoral Science Foundation under Grant Number 2023M733678;the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0750100);the National Natural Science Foundation of China(No.22193051).
INTRODUCTION Structural analogues of chlorinated paraffins(CPs)are compounds that contain the chlorinated n-alkanes skeleton of CPs and other functional groups.Recently,some structural analogues of CPs at high levels ...
The direct alkylation of benzene with alkanes is an effective method for alkylbenzene production.Our group previously discovered that a mixture of supported Pd nanoparticles and solid acids effectively promoted the al...
Brominated-chlorinated paraffins(Br-CPs)are a comparably new compound class that features both Cl and Br atoms on one or several alkane backbones.Due to legal restrictions in the use of conventional chlorinated paraff...
The selective functionalization of C(sp^(3))–H bonds with subtle differences in alkanes is highly sought after due to its atom-and step-efficiency.The activation of C(sp^(3))–H bonds through hydrogen atom transfer(H...
funding from KU Leuven(C14/23/090,C14/19/079);the Research Foundation Flanders(FWO)(G082218N,GF9118N);FWO and F.R.S.-FNRS under the excellence of science(EOS)program(grant 30489208);Li-Hua Yu and Tianze Hu gratefully acknowledge financial support through the China Scholarship Council(CSC 201908350094,CSC 202006150018).
Self-assembled molecular networks(SAMNs)formed on crystalline solid substrates result from the spontaneous arrangement of individual molecules into structured patterns.The interaction between molecules and the substra...
National Key R&D Program of China (No.2018YFA0901101);the National Natural Science Foundation of China (Nos.22193050,92043301,22176203 and 22276212);the Sanming Project of Medicine in Shenzhen (No.SZSM201811070)。
Investigating the development toxicity of perfuorinated iodine alkanes(PFIs)is critical,given their estrogenic effects through binding with estrogen receptors(ERs).In the present study,two PFIs,including dodecafuoro-1...
supported by the National Key Research and Development Program of China(2022YFC2804105);the Joint Fund of Shandong Natural Science Foundation(ZR2021LSW013);Natural Science Foundation of Shandong Province(ZR2020QB044,ZR2020QH364,ZR2023MH245,and ZR2022QB090);Postdoctoral Science Foundation of China(2020M682157);Qingdao Emerging Industry Cultivation Project in 2023(23-1-4-xxgg-19-nsh);Shandong Provincial Science and Technology SME Innovation Capacity Improvement Project(2022TSGC2204);the National Natural Science Foundation of China(82003787);Postdoctoral Innovation Project of Shandong Province。
The ability to selectively introduce diverse functionality onto hydrocarbons is of substantial value in the synthesis of both small molecules and pharmaceuticals.In this endeavour,as a photocatalyst-and metalfree proc...
the financial support from National Natural Science Foundation of China(21838006,21776159);National Key Research and Development Program of China(2018YFC1902101)。
To produce paraffin from hydrogenation/deoxygenation of palmitic acid,model compound of bio-oil obtained by hydrothermal liquefaction(HTL)of microalgae has been an attractive focus in recent years.In order to avoid en...