STERIC

作品数:66被引量:104H指数:5
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相关领域:理学更多>>
相关作者:李焕张生万李美萍夏幼南更多>>
相关机构:山西大学佐治亚理工学院清华大学更多>>
相关期刊:《National Science Review》《Advances in Atmospheric Sciences》《Health Data Science》《Acta Oceanologica Sinica》更多>>
相关基金:国家自然科学基金年山西省研究生优秀创新项目中国博士后科学基金国家高技术研究发展计划更多>>
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Dynamic steric confinement effect expands the frontier of Cu-catalyzed asymmetric propargylic aminations
《Science China Chemistry》2024年第10期3181-3183,共3页Peng Chen Mao-Mao Zhang Wen-Jing Xiao Liang-Qiu Lu 
Chiralα-tertiary amines and related azacycles are commonly found in many natural products,pharmaceuticals and agrochemicals[1].Copper-catalyzed asymmetric propargylic amination(APA)reactions have been established as ...
关键词:CATALYZED ASYMMETRIC AMINES 
Steric Control over Interligand Dihedrals and Splay Leads to the Formation of Fe^(II)_(6)L_(6)and Fe^(II)_(8)L_(8)Antiprisms
《CCS Chemistry》2024年第10期2411-2419,共9页Yuchong Yang Yuyin Du Tanya K.Ronson Jonathan R.Nitschke 
supported by the European Research Council(grant no.695009);the UK Engineering and Physical Sciences Research Council(EPSRC,grant nos.EP/T031603/1 and EP/P027067/1).
Macrocycles have found uses in guest capture,sensing,and porous materials,motivating the development of new methods for their synthesis.Here we report the construction of two types of barrelshaped macrocyclic assembli...
关键词:self-assembly metal-organic cages host-guest chemistry redox-responsive materials dihedral control 
Concerted Steric and Electronic Strategy in Thermostable Salicylaldiminato Nickel Catalysts for Ethylene(Co)polymerization
《Chinese Journal of Polymer Science》2024年第8期1085-1092,共8页Hong-Yu Ji Hong-Liang Mu Chun-Feng Tang Yu-Xing Zhang Yue Chi Zhong-Bao Jian 
financially supported by the National Natural Science Foundation of China(Nos.22122110 and U23B6011 for Z.J.);the Jilin Provincial Science and Technology Department Program(No.20210101070JC for Y.C.)。
Olefin polymerization is one of the most im portant chemical reactions in industry.This work presents a strategy that emphasizes the synergistic meta/poro-steric hindrance of N-aryl groups and electronic effects in ne...
关键词:POLYOLEFIN Salicylaldiminato ligand Nickel catalyst Oil WAX 
“Steric Armor”Strategy of Blue Fluorescent Emitters against Photooxidation-Induced Degradation
《Chinese Journal of Chemistry》2024年第11期1223-1229,共7页Sha-Sha Wang Jing-Rui Zhang Kuan-De Wang Hao-Ran Li Peng-Hui Meng Yang Zhou Xiang Yu Ying Wei Quan-You Feng Yu-He Kan Ling-Hai Xie 
supported by the Natural Science Foundation of Nanjing University of Posts and Telecommunications(NY222157,NY221085);State Key Laboratory of Organic Electronics and Information Display(GZR2022010008);Key Laboratory of Low-dimensional Materials Chemistry of Jiangsu Province(JSKC20022);General Program of China Postdoctoral Science Foundation(2022M711684);General Program of Basic Science(Natural Science)of Colleges and Universities of Jiangsu Province(22KJB430036);National Overseas Study Fund(202008320051);National Key Laboratory(2009DS690095);the National Natural Science Foundation of China(62288102).
Stability against oxygen is an important factor affecting the performance of organic semiconductor devices.Improving photooxidation stability can prolong the service life of the device and maintain the mechanical and ...
关键词:Organic semiconductor PHOTOOXIDATION Spirocyclic aromatic hydrocarbons Crystal engineering Fluorescence 
G protein-coupled receptors(GPCRs):advances in structures,mechanisms,and drug discovery被引量:1
《Signal Transduction and Targeted Therapy》2024年第5期1938-1980,共43页Mingyang Zhang Ting Chen Xun Lu Xiaobing Lan Ziqiang Chen Shaoyong Lu 
This study was supported by grants from the National Key R&D Program of the Ministry of Science and Technology(No.2023YFC3404700);the National Natural Science Foundation of China(No.22077082);the Shanghai Frontiers Science Center of Cellular Homeostasis and the Human Diseases,and the Innovative Research Team of High-Level Local Universities in Shanghai.
G protein-coupled receptors(GPCRs),the largest family of human membrane proteins and an important class of drug targets,play a role in maintaining numerous physiological processes.Agonist or antagonist,orthosteric eff...
关键词:STERIC DESIGNING MECHANISMS 
Terminal-selective C(sp^(3))-H borylation of unbranched alkanes enabled by intermolecular radical sampling and LMCT photocatalysis
《National Science Review》2024年第5期89-91,共3页Zhexuan Lei Jie Wu 
The selective functionalization of C(sp^(3))–H bonds with subtle differences in alkanes is highly sought after due to its atom-and step-efficiency.The activation of C(sp^(3))–H bonds through hydrogen atom transfer(H...
关键词:BONDS ALKANES STERIC 
Fine-tuning the activation behaviors of ternary modular cabazitaxel prodrugs for efficient and on-target oral anti-cancer therapy
《Asian Journal of Pharmaceutical Sciences》2024年第2期188-203,共16页Mingyang Zhang Yifan Miao Can Zhao Tong Liu Xiyan Wang Zixuan Wang Wenxin Zhong Zhonggui He Chutong Tian Jin Sun 
supported by National Natural Science Foundation of China(No.82173766,82104109);Natural Science Foundation of Liaoning Province(2022-BS158);Liaoning Province Applied Basic Research Program(No.2022JH2/101300097);National Key R&D Program of China(No.2022YFE0111600).
The disulfide bond plays a crucial role in the design of anti-tumor prodrugs due to its exceptional tumor-specific redox responsiveness. However, premature breaking of disulfide bonds is triggered by small amounts of ...
关键词:Steric disulfide bond Triglyceride-like pr odrugs CABAZITAXEL Lymphatic transport Oral chemotherapy 
A Structure-Based Allosteric Modulator Design Paradigm
《Health Data Science》2023年第1期90-101,共12页Mingyu Li Xiaobin Lan Xun Lu Jian Zhang 
the Shanghai Jiao Tong University School of Medicine and Ningxia Medical University for their support of this research project.Funding:This research was supported in part by grants from the National Key R&D Program of China(2022YFF1203005);the National Natural Science Foundation of China(22077082,21778037,81925034,91753117,and 81721004);the Innovation Program of Shanghai Municipal Education Commission(2019-01-07-00-01-E00036,China);the Shanghai Science and Technology Innovation(19431901600,China);the Shanghai Health and Family Planning System Excellent Subject Leader and Excellent Young Medical Talents Training Program(2018BR12,China).
Importance:Allosteric drugs bound to topologically distal allosteric sites hold a substantial promise in modulating therapeutic targets deemed undruggable at their orthosteric sites.Traditionally,allosteric modulator ...
关键词:STERIC RATIONAL holds 
Insights into the adsorption performance and mechanism of Cr(Ⅵ)onto porous nanocomposite prepared from gossans and modified coal interface:Steric,energetic,and thermodynamic parameters interpretations被引量:1
《Chinese Journal of Chemical Engineering》2023年第9期118-128,共11页Mohamed Mobarak Saleh Qaysi Mohamed Saad Ahmed Yasser F.Salama Ahmed Mohamed Abbass Mohamed Abd Elrahman Hamdy AAbdel-Gawwad Moaaz K.Seliem 
supported by Researchers Supporting Project number(RSP2023R455),King Saud University,Riyadh,Saudi Arabia。
Herein,iron oxide/hydroxides deposits(gossans)were utilized,for the first time,in the fabrication of magnetite nanoparticles(MNPs)to load modified coal(MC).The as-synthesized MNPs@MC composite was characterized via di...
关键词:COAL Magnetic nanoparticles Cr(Ⅵ)adsorption Statistical models Thermodynamic parameters 
Spiro-based triphenylamine molecule with steric structure as a cathode material for high-stable all organic lithium dual-ion batteries
《Journal of Energy Chemistry》2023年第8期24-31,I0003,共9页Liya Huang Zehao Yu Liubin Wang Bin Qin Fengshi Cai Zhihao Yuan Zhiqiang Luo 
supported by the National Natural Science Foundation of China (21905205 and 22109037);the Natural Science Foundation of Tianjin City (20JCYBJC00380);the Advanced Talents Incubation Program of Hebei University (521000981408);the Haihe Laboratory of Sustainable Chemical Transformations(YYJC202110)。
Redox p-type organic compounds are promising cathode materials for dual-ion batteries.However,the triphenylamine-based polymers usually with agglomerate and intertwined molecular chain nature limit the maximum reactio...
关键词:Spiro-basedmolecule Cathodematerial P-typeorganiccompounds Longcycling life All organic lithiumdual-ionbatteries 
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