supported by the National Key Research and Development Program of China(2022YFC2804105);the Joint Fund of Shandong Natural Science Foundation(ZR2021LSW013);Natural Science Foundation of Shandong Province(ZR2020QB044,ZR2020QH364,ZR2023MH245,and ZR2022QB090);Postdoctoral Science Foundation of China(2020M682157);Qingdao Emerging Industry Cultivation Project in 2023(23-1-4-xxgg-19-nsh);Shandong Provincial Science and Technology SME Innovation Capacity Improvement Project(2022TSGC2204);the National Natural Science Foundation of China(82003787);Postdoctoral Innovation Project of Shandong Province。
The ability to selectively introduce diverse functionality onto hydrocarbons is of substantial value in the synthesis of both small molecules and pharmaceuticals.In this endeavour,as a photocatalyst-and metalfree proc...
This work was financially supported by the National Natural Science Foundation of China(grant nos.22122701,21731004,91953201,92153303,21977044,and 21907050);the Natural Science Foundation of Jiangsu Province(grant nos.BK20202004 and BK20190282);the Excellent Research Program of Nanjing University(grant no.ZYJH004).
Photodynamic therapy(PDT)usually shows limited efficacy in solid tumors since traditional PDT is O_(2)^(-)dependent while solid tumors are inherently hypoxic.In addition,hypoxic tumor cells possess antiapoptotic pathw...
supported by the Institute for Basic Science(IBS-R010-A2)。
Bifunctional reagents that serve as dual coupling partners with an activating species have emerged as valuable synthetic tools in organic chemistry.They allow for the development of diverse reaction modes with enhance...
support from the National Natural Science Foundation of China(grant no.21971266).
β-Amino acids(AAs),homologs ofα-AAs,are important building blocks of biological materials.Herein,chiral recognitions ofβ-AAs with Ir(III)complexes are reported,in favor of formation of the thermodynamically stable...
the financial support from the National Natural Science Foundation of China(grant no.21971266).
The diastereoselective photoreactions of Ir(III)-amine and Ir(III)-diamine complexes are observed in the presence of O2.TheɅ-[Ir(pq)_(2)(R-mapy)](PF_(6))(pq is 2-phenylquinoline and mapy is 2-(1-aminoethyl)pyridine)di...
supported by the National Natural Science Foundation of China (21877011, 21576038, 21421005);the Fundamental Research Funds for the Central Universities of China (DUT16TD21);Science Program of Dalian City (2014J11JH133, 2015J12JH207);the Supercomputing Center of Dalian University of Technology
Photochromic diarylethenes have been widely used in many fields. However, their cyclization process must be induced by UV light. In this article, a simple strategy is developed by extending π-conjugation with electro...
financial support from the Ministry of Science and Technology of China(2013CB834804,2013CB834505and 2014CB239402);the National Natural Science Foundation of China(21572090,21390404 and 91427303);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17030200);the Chinese Academy of Sciences
In recent years, visible-light-driven organic reactions have been experiencing a significant renaissance in response to topical interest in environmentally friendly green chemical synthesis. The transformations using ...
We are grateful for the financial supports from the National Natural Science Foundation of China(Nos.21372055 and 21272047);the State Key Laboratory of Urban Water Resource and Environment(SKLUWRE)(No.2012DX10);the Fundamental Research Funds for the Central Universities(No.HIT.BRETIV.201310);the Zhejiang Natural Science Foundation(No.LY12B02009).
The photochemical behavior of bicyclo[2.1.1]hexyl derivatives was investigated by irradiation with a 450 W medium-pressure mercury lamp in acetonitrile solution.The irradiation of methyl bicyclo[2.1.1]hexane-5-carbony...
Supported by the National Natural Science Foundation of China(No.20904007)
The density functional theory(DFT) calculations were performed to investigate a typical Norrish/Yang type II photoreaction of 5-methylbicyclo[1.1.1]-pentanyl ketone.The results reveal the essential correlation betwe...
We are grateful to the financial supports from the National Natural Science Foundation of China (Nos. 20802013, 21002018, 21072038), the Natural Scientific Research Innovation Foundation in Harbin institute of Technology (Nos. 01107866, 01107986) and the Wenzhou Science and Technology Program (No. G20100056).
The first example of the p-orbital overlap controlled enantioselectivity of Norrish type II photocyclization reaction was described. Irradiation of 5-methyl bicyclo[l. 1.1 ]pentanyl ketone with UV in the solid state a...