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the National Natural Science Foundation of China(Nos.82073997 and 22001024);the Science&Technology Department of Sichuan Province(Nos.2021YFS0044 and 2021YJ0402);Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-D-202209);Xinglin Scholar Research Promotion Project of Chengdu University of TCM.
The scope of stereochemistry recognition usually occurs near the chiral scaffold of a ligand or catalyst.Remote stereocontrol,which can surpass the limits of stereorecognition of remote prochiral centers,has long been...
supported by the National Natural Science Foundation of China(NSFC)(21772031);the Natural Science Foundations of Hebei Province(B2019201398).
Different novel fused multicyclic iminosugars were synthesized from D-ribose tosylate,aniline and vinyl ethyl ether by one-pot three-component stereoselective[4+2]reaction at different temperatures.The iminium-ion is ...
the National Key Research and Development Program of China(2022YFA1503502);National Natural Science Foundation of China(U21B20101,21932006,and 22202175);China Postdoctoral Science Foundation(2021M700119).
Selective hydrogenation over earth-abundant metal catalysts is challenging but particularly valuable for practical applications in heterogeneous catalysis.Herein,we demonstrate that the catalytic selectivity of the co...
Financial support from the National Natural Science Foundation of China(No.21602052);the start-up funding from Wuhan University(Nos.691000002 and 600460026)are gratefully acknowledged.The authors thank Prof.Dr.Xianggao Meng(Central China Normal University)for performing the X-ray crystal analysis.
The rapid collection of a library of biologically relevant molecules is essential in new drug discovery.Here we show a variety of bioactive 1,3-indanedione-based spirocyclic tetrahydroquinolines that have been concise...
the Shenzhen Overseas High-level Talents Innovation Plan of Technical Innovation Project(No.KQJSCX20180319114439973)for financial support.
A highly efficient kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via Rh-catalyzed asymmetric hydroarylation has been described for the first time.A variety of arylboronic acids coupled with 2-subst...
supported by the National Natural Science Foundation of China(Nos.21866032,21805191);China Postdoctoral Science Foundation(No.2020M672811);the Guangdong Basic and Applied Basic Research Foundation(No.2020A151501982);the“Explorer 100”cluster system of Tsinghua National Laboratory for Information Science and Technology。
The conversion of chemical feedstock materials into high value-added products accompanied with dehydrogenation is of great value in the chemical industry.However,the catalytic dehydrogenation reaction is inhibited by ...
The asymmetric photocatalytic organic synthesis(APOS)process is a sustainable and environmentally benign method for the production of optically active chemicals with sunlight as an energy source.However,it still lacks...
Supported by the foundation of the Department of Education of Guangdong Province(2016KTSCX144,2017KZDXM085);Natural Science Foundation of Hunan Province(No.2018JJ3196);the High-level Scientific Research Foundation for the introduction of talent(AL2018008)
A novel and efficient Ir-catalyzed 1,4-and 1,2-addition of diphenylphosphine oxide to quinolines was developed to obtain various 1,2,3,4-tetrahydroquinoline-2,4-diyl(bisdiphenylphosphine oxide) derivatives. The stru...
An atom economical highly efficient method has been developed for the synthesis of quinoline and 1,2,3,4-tetra- hydroquinoline derivatives from o-nitrotoluenes bearing electron-withdrawing groups and olefins (acrylic...
National Natural Science Foundation of China(Grant No.21372019)
An efficient synthesis of tetrahydrofuro[3,2-b]quinolin-2(3H)-ones from α-angelica lactone and 2-aminobenzaldehydes via a tandem Aldol-Michael addition is described. The reactions were carried out using DBU as the ...