Cu^(26+)离子里德堡系列的电离能和量子数亏损  

Ionization Energy and Quantum Defects of Rydberg Series for Cu^(26+) Ion

作　　者：王丽[1] 李印[1] 

机构地区：[1]营口理工学院,辽宁营口115014

出　　处：《河北科技师范学院学报》2017年第4期60-63,共4页Journal of Hebei Normal University of Science & Technology

摘　　要：应用全实加关联(FCPC)方法,计算了类锂Cu^(26+)离子1s^2nl(l=d,f;n≤9)2个里德堡系列电离能,得到的计算结果与现有的实验数据高度符合;结合量子数亏损理论,确定了类锂Cu^(26+)离子1s^2nl(l=d,f;n≤9)态的量子数亏损;分析了量子数亏损随着主量子数n和轨道角动量l的变化规律;在此基础上,根据半经验方法实现了对高激发态的能量的理论预言。Ionization energy of the ls2n/（ l = d, f; n≤9） Rydberg series for Li-hke Cu26＋ ion were calculated by using the Full-Core Plus Correlation （FCPC） method. Compared with the existing experimental data availa- ble in the literature, it appeared that the agreement of our total energies and ionization energy with them was satisfactory. The quantum defects of ls2nl（l = d, f; nv9） stated that the Li-like Cu26＋ ion was determined according to the quantum defect theory. The regularity about quantum defect on principle quantum number n and orbital angular moment l had been analyzed. Combining with semi-empirical method, the theoretical prediction on the energy of this ion might be extrapolated to the higher excited states.

关 键 词：Cu^26+离子 电离能 FCPC方法 量子数亏损 半经验方法 

分 类 号：O562.1[理学—原子与分子物理]