有机光伏应用中PVK-C_(60)共聚物性能增强研究  

Performance Enhancement of Poly (N-vinylcarbazole) with Covalently Bonded C_(60) for Photovoltaic Application

作　　者：蒋曲博[1,2] 甘永进 梁国令 甘国妹 胡良红 宁维莲 JIANG Qubo;GAN Yongjin;Liang Guoling;GAN Guomei;HU Lianghong;NING Weilian(School of Electronic Engineering and Automation, Guilin University of Electronic Technology, Guilin, 541004, CHN;School of Electronics and Cornrnunication Engineering, Yulin Normal University, Yulin , Guangxi, 537000, CHN;Guangxi Key Laboratory of Optoelectronic Information Processing, Guilin , 541004, CHN)

机构地区：[1]桂林电子科技大学电子工程与自动化学院,桂林541004 [2]广西光电信息处理重点实验室,桂林541004 [3]玉林师范学院电子与通信工程学院,广西玉林537000

出　　处：《固体电子学研究与进展》2018年第2期146-149,共4页Research & Progress of SSE

基　　金：国家自然科学基金资助项目(61565004);广西高校中青年教师基础能力提升项目(2017KY0545);广西高校科研项目(KY2015YB109);广西自然科学基金资助项目(2014GXNSFGA118003);广西自动检测技术与仪器重点实验室基金资助项目(YQ16103)

摘　　要：相比于由聚N-乙烯咔唑和C_(60)混合而成的混合物材料,在相同条件下,由聚N-乙烯咔唑与C_(60)共价结合所得的聚合物材料(PVK-C_(60))所组成的光伏器件的性能得到显著的提高。在PVK-C_(60)共聚物中,咔唑团充当施主,共价结合的球壳状碳分子(富勒烯)C_(60)充当受主。开路电压从混合物器件的0.25V提高到了PVK-C_(60)共聚物器件的大于1V。PVK-C_(60)的吸收边扩展到了整个可见光光谱范围,而它们的简单混合物在这个范围内只有非常弱的吸收。光致发光光谱显示,PVK-C_(60)共聚物较之它们的简单混合物有着更明显的光谱猝灭,这意味着在PVK-C_(60)共聚物中,施主(咔唑)和受主(C_(60))的结合状态更好。In this paper,it is found that the photovoltaic device based on the copolymer of poly（N-vinylcarbazole）with covalently bonded C60（PVK-C60）exhibits significant performance enhancement compared to that based on the simple blend of poly（N-vinylcarbazole）and C60.In PVK-C60copolymer,the carbazole block acts as donor and covalently attached fullerene（C60）acts as acceptor.The open circuit voltage（V_（oc））is increased from 0.25Vfor the blend to more than 1V for PVK-C60copolymer.The absorption edge of PVK-C60 extends through the entire visible spectrum,while the blend has very weak absorption in this range.PL spectrum shows that there is more obvious spectrum quenching for PVK-C60copolymer than the blend which implies wellmixed states of donor（carbazole）and acceptor（C60）in PVK-C60copolymer.

关 键 词：聚N-乙烯咔唑 混合物材料 光伏器件 共价结合 光谱 

分 类 号：O621.2[理学—有机化学]