One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6  

作　　者：Chongwen Jiang Jundong Zhu Bing Wang Lu Li Hong Zhong 

机构地区：[1]College of Chemistry and Chemical Engineering Central South University, Changsha 410083, China [2]Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha 410083, China

出　　处：《Chinese Journal of Chemical Engineering》2018年第6期1270-1277,共8页中国化学工程学报（英文版）

基　　金：Supported by the National Natural Science Foundation of China(21476267);the China–Japan International Cooperation Project(2013DFG50150);the Hunan Provincial Science and Technology Department Plan Project(2016TP1007)

摘　　要：Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method.Various characterization techniques confirm that highly distributed ZrO_2 nanoparticles and multicoordinated Zr^(4+) species are incorporated in the mesoporous composites.One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system.The effects of temperature,reaction time,catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated.It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system,respectively.Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method.Various characterization techniques confirm that highly distributed ZrO2 nanoparticles and multicoordinated Zr^（4＋） species are incorporated in the mesoporous composites.One-pot synthesis of 5-hydroxymethylfurfura（HMF） from glucose was examined in the presence of Zr-KIT-6（20） the molar ratio of Si to Zr is 20 under aqueous system.The effects of temperature,reaction time,catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated.It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system,respectively.Both the acidity of Zr-KIT-6（20） and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.

关 键 词：GLUCOSE ONE-POT Dehydration 5-HMF Hydrothermal Mesoporous KIT-6 

分 类 号：TQ251.11[化学工程—有机化工]