Reaction Characteristics of Polysaccharide-Iodine Complexes: A Mini-review  

作　　者：GenQue Fu Nan Li YaJie Hu PanPan Yue Feng Peng 

机构地区：[1]Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University

出　　处：《Paper And Biomaterials》2018年第2期64-75,共12页造纸与生物质材料（英文）

基　　金：supported by the Fundamental Research Funds for the Central Universities(JC2015-03);National Natural Science Foundation of China(31470417);Beijing Municipal Natural Science Foundation(6182031);Author of National Excellent Doctoral Dissertations of China(201458)

摘　　要：The potential reactions between natural polysaccharides and iodine and their products have been explored for a long time. Due to the complex factors that can in？uence these reactions, a clear-cut mechanism has not yet been developed. Starch-iodine complexes, especially the amylose-iodine complex, are the most investigated of the polysaccharide-iodine reactions, and the study of this reaction can be used as a basis for the investigation of other polysaccharide-iodine reactions. In this paper, significant aspects of the reaction were introduced, including the influence of the polysaccharide structure on the properties of the resulting complexes, the relationship between the concentration of CaCl2 and formation of the final products, as well as the form of the polyiodides in these complexes. The interior structure and the surface morphology of the complexes were discussed, along with the progress in research related to this reaction.The potential reactions between natural polysaccharides and iodine and their products have been explored for a long time. Due to the complex factors that can influence these reactions, a clear-cut mechanism has not yet been developed. Starch-iodine complexes, especially the amylose-iodine complex, are the most investigated of the polysaccharide-iodine reactions, and the study of this reaction can be used as a basis for the investigation of other polysaccharide-iodine reactions. In this paper, significant aspects of the reaction were introduced, including the influence of the polysaccharide structure on the properties of the resulting complexes, the relationship between the concentration of CaCl_2 and formation of the final products, as well as the form of the polyiodides in these complexes. The interior structure and the surface morphology of the complexes were discussed, along with the progress in research related to this reaction.

关 键 词：AMYLOSE hemicelluloses I2-KI POLYIODIDE POLYSACCHARIDES 

分 类 号：TQ281[化学工程—有机化工] O641.4[理学—物理化学]