全二维气相色谱用于航天煤油组成的研究  

Research of Components in Rocket Kerosene by Comprehensive Two-Dimensional Gas Chromatography

作　　者：任春波 沈兆欣 马晨菲[2] 吴庆元[1] REN Chun-bo;SHEN Zhao-xin;MA Chen-fei;WU Qing-yuan(Beijing Aerospace Institute for MetrologT and measurement Technology,Beijing 100076,China;Petrochemical research institute,China National Petroleum Corporation,Beijing 100195,China)

机构地区：[1]北京航天计量测试技术研究所,北京100076 [2]中国石油天然气股份有限公司石油化工研究院,北京100195

出　　处：《宇航计测技术》2018年第4期90-94,共5页Journal of Astronautic Metrology and Measurement

摘　　要：利用全二维气相色谱,结合飞行时间质谱和火焰离子化检测器,对航天煤油组成进行了定性和定量分析,根据试验结果分析了族组成、碳数分布与航天煤油性能之间的关系。研究结果表明:该航天煤油主要由异构烷烃、单环环烷烃、双环环烷烃组成,具有高燃烧值和良好的稳定性。研究结果可以为航天煤油组成的分析和优化提供依据。Two-dimensional gas chromatography combined with time of flight mass spectrometry and flame ionization detector were applied for quantitive and qualitative analysis of rocket kerosene. The relationships between group-type,carbon-number distribution and capability of rocket kerosene were investigated based on the experimental data. The results show that the rocket kerosene mainly comprises isoparaffins,cycloalkanes,bicyclic alkanes. Special composition made for high combustion value and excellent stability. This research results can be used for the analysis and optimization of rocket kerosene components.

关 键 词：煤油 气相色谱法 碳数 

分 类 号：X169[环境科学与工程—环境科学]