Calcium-catalyzed reactions of element-H bonds  

作　　者：Lei Yu Rongrong Qian Xin Deng Fang Wang Qing Xu 

机构地区：[1]School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China [2]Jiangsu College of Tourism, Yangzhou 22S127, China [3]Yangzhou Polytechnology Institute, Yangzhou 225127, China

出　　处：《Science Bulletin》2018年第15期1010-1016,共7页科学通报（英文版）

基　　金：supported by the National Natural Science Foundation of China(21202141,21672163);Priority Academic Program Development(PAPD) of Jiangsu Higher Education Institutions;Top-notch Academic Programs Project of Jiangsu Higher Education Institutions(TAPP);the Open Project Program of Jiangsu Key Laboratory of Zoonosis(R1509);the Natural Science Foundation of Guangling College(ZKZD17005)

摘　　要：Investigation on organocalcium catalysis is just unfolding during the past decade. Beside conventional Ca salts with strong electron-withdrawing counter anions that may serve as Lewis acid catalysts, many Ca complexes have also been designed recently and found to be good catalysts in activation of element-H （E-H） bonds like transition metal catalysts. These findings are interesting and may attract the interest of the chemists. Due to the great abundance, non-toxicity, and biocompatible features of Ca element, Ca-catalyzed reactions can be of great significance from the viewpoint of industry. This short review summarizes the recent advances on Ca-catalyzed reactions of E-H bonds. We hope that it may provide a useful guide for interested readers from both the academy and industry.Investigation on organocalcium catalysis is just unfolding during the past decade. Beside conventional Ca salts with strong electron-withdrawing counter anions that may serve as Lewis acid catalysts, many Ca complexes have also been designed recently and found to be good catalysts in activation of element-H(EAH) bonds like transition metal catalysts. These findings are interesting and may attract the interest of the chemists. Due to the great abundance, non-toxicity, and biocompatible features of Ca element,Ca-catalyzed reactions can be of great significance from the viewpoint of industry. This short review summarizes the recent advances on Ca-catalyzed reactions of EAH bonds. We hope that it may provide a useful guide for interested readers from both the academy and industry.

关 键 词：CALCIUM Organic reaction Green chemistry ADDITION Hydrofunctionalization 

分 类 号：O621.251[理学—有机化学]