GC-MS法测定不同包装酱油、醋中16种邻苯二甲酸酯类塑化剂含量研究  

Study on GC-MS determination of 16 kinds of PAEs plasticizer in soy sauce and vinegar with different packages

作　　者：程寿峰 王婕[2] 刘开茂 张爱华 CHENG Shoufeng;WANG Jie;LIU Kaimao;ZHANG Aihua(School of Public Health,Guizhou Medical University,Key Laboratory of Environment Pollution Monitoring and Disease Control,Ministry-of Education,Guiyang,Guizhou 550025,China;Department of Information,44 Hospital of the PLA,Guiyang,Guizhou 550009,China)

机构地区：[1]贵州医科大学公共卫生学院环境污染与疾病监控教育部省部共建重点实验室,贵州贵阳550025 [2]解放军44医院信息科,贵州贵阳550009

出　　处：《贵州师范大学学报（自然科学版）》2018年第5期90-94,120,共6页Journal of Guizhou Normal University：Natural Sciences

基　　金：贵州省科技厅联合基金项目(黔科合J字[2016]7374)

摘　　要：通过用正己烷提取,GC/MS选择离子扫描模式(SIM)进行检测,建立酱油、醋中16种塑化剂含量的GC-MS检测方法。16种塑化剂在50~2 000μg/kg范围内,均呈良好的线性关系,相关系数R在0.995 6~0.999 5之间。0.05 mg/kg、0.10 mg/kg、0.20 mg/kg的3个浓度溶液回收率在90.8%~103.5%之间,相对标准偏差在3.2%~8.6%之间。所建立的方法操作简单、精密度高、快速,适合酱油、醋中塑化剂的检测。the paper reports a GC-MS method for determination of 16 kinds of PAEs platicizer in soy sauce and vinegar, the sample will be extracted with n-hexane and determined with SIM that was chosen in GC/MS. 16 kinds of PAEs plasticizer got a good linearity between 50 -2 000 μg/kg and the correlation was from 0. 995 6 to 0. 999 5. The mean recoveries were from 90.8% to 103.5% , with the different solution concentration of 0.05 mg/kg, 0.10 mg/kg and 0.20 mg/kg, and the RSDs were from 3.2% to 8.6%. The method was so simple, rapid and with satisfactory recoveries that it could be used in the determination of plasticizer in soy sauce and vinegar.

关 键 词：GC—MS 塑化剂 酱油 醋 

分 类 号：O657.63[理学—分析化学] R155.5[理学—化学]