橡胶食品输送管中抗氧剂2246的检测及其迁移研究  

Study on determination method and migration of antioxidant 2246 in food contact rubber pipes

作　　者：胡光辉[1] 史迎杰 钱冲[1] 李琴梅[1] 高峡[1] 刘伟丽[1] Hu Guanghui;Shi Yingjie;Qian Chong;Li Qinmei;Gao Xia;Liu Weili(Beijing Key Laboratory of Organic Materials Testing Technology and Quality Evaluation, Key Laboratory of Analysis and Testing, Beijing Academy of Science and Technology, Beijing Engineering Research Center of Food Safety Analysis, Beijing Centre for Physical and Chemical Analysis, Beijing 100089, China)

机构地区：[1]北京市理化分析测试中心有机材料检测技术与质量评价北京市重点实验室北京市科学技术研究院分析测试技术重点实验室北京市食品安全分析测试工程技术研究中心,北京100089

出　　处：《分析仪器》2018年第5期115-119,共5页Analytical Instrumentation

基　　金：北京市科学技术研究院青年骨干计划(201526)

摘　　要：建立了气相色谱-质谱法测定食品接触橡胶制品中抗氧剂2246的检测方法。通过优化前处理方法 ,确定以丙酮为提取溶剂,采用直接回流法进行3小时提取后对抗氧剂2246含量进行测定。结果表明该方法准确度高,检出限为2mg/kg。迁移实验结果证明,在10%乙醇和橄榄油食品模拟液中抗氧剂2246的迁移量相对较高,在蒸馏水食品模拟液中的迁移量明显低于其他模拟物中的迁移量,且随温度的升高抗氧剂2246的迁移速率加快。The method for determination of antioxidant 2246 in food contact rubber pipes was developed by gas chromatography mass spectrometry （GCMS）. After reflux extraction for 3 hours with acetone as the extraetant, the content of antioxidant 2246 was determined by GCMS. The results showed that this method was accurate, and the limit of detection was 2 mg/kg. The results of migration research proved that the migration of antioxidant 2246 in the 10% ethanol and the olive oil simulants was much higher than that in the distilled water simulant. Furthermore, the migration of antioxidant 2246 was accelerated with the increase of temperature.

关 键 词：橡胶管 抗氧剂2246 检测 迁移 

分 类 号：TS207.3[轻工技术与工程—食品科学]