四组分隔板塔用于三氯氢硅分离的模拟研究  

Simulation of Four-Product Dividing Wall Columns for the Separation of Trichlorosilane

作　　者：王素贤 何银凤 高亚丽 王燕[2] 朱怀工[3] Wang Suxian;He Yinfeng;Gao Yali;Wang Yan;Zhu Huaigong(Huanghe Hydropower Photovoltaic Industry Technology Co.Ltd.Qinghai Branch,Xining 810007,China;School of Chemical Engineering and Technology,Tianjin University,Tianjin 300350,China;Peiyang Chemical Equipment Co.,Ltd.,Tianjin 300072,China)

机构地区：[1]青海黄河上游水电开发有限公司光伏产业技术分公司,西宁810007 [2]天津大学化工学院,天津300350 [3]天津市天大北洋化工设备有限公司,天津300072

出　　处：《化学工业与工程》2018年第5期72-79,共8页Chemical Industry and Engineering

摘　　要：对用于四组分分离的Kaibel隔板塔和完全热耦合隔板塔4-DWC在多晶硅还原工段中分离三氯氢硅的应用进行了模拟研究。首先,将不同结构的复杂塔简化为在热力学上等效的简单塔序列流程,利用简捷法设计计算得到初值;再利用严格模拟进行参数优化和模拟计算。结果表明:与常规三塔顺序分离流程相比,Kaibel隔板塔可节约能耗26.43%,4-DWC节约能耗36%,设备数量大大减少。Two four-product dividing wall columns,Kaibel Dividing Wall Column（ Kaibel DWC） and fully thermally coupled Dividing Wall Column（ 4-DWC）,were proposed as innovation process to separate trichlorosilane from reduction plant in polycrystalline silicon system. Using commercial software packages of Aspen Plus,Kaibel DWC and 4-DWC can be simulated by employing corresponding thermodynamically equivalent sequences of simple columns. Based on reliable estimates by the short-cut method,the rigorous steady-state simulation of the Kaibel DWC was obtained. The structure parameters and the operation parameters were optimized. The simulation results indicated that compared with the conventional configuration for the Kaibel DWC and 4-DWC,the energy saving were 26. 43% and 36%,respectively,and the equipment investment was reduced.

关 键 词：Kaibel隔板塔 完全热耦合 多晶硅 三氯氢硅 

分 类 号：TQ053.5[化学工程]