HCFC-141b制冷剂气体水合物生长过程的形态  

HCFC-141b REFRIGERANT GAS HYDRATE FORMATION MORPHOLOGY

作　　者：赵永利[1] 郭开华[1] 樊栓狮[1] 梁栋[1] 舒碧芬[1] 刘勇[1] 葛新石[2] 

机构地区：[1]中国科学院广州能源研究所,广东广州510070 [2]中国科学技术大学热能工程系,安徽合肥430070

出　　处：《化工学报》2002年第9期907-911,共5页CIESC Journal

基　　金：国家自然科学基金重点资助项目 (No 5 9836 2 30 );国家基础研究规划基金资助项目 (No G2 0 0 0 0 2 6 30 6 )~~

摘　　要：通过实验观测了HCFC - 141b制冷剂气体水合物的生成过程 ,认为水相和制冷剂相在过冷的条件下在界面上局部成核 ,成核扩展至两相接触的整个界面 ,水合物的进一步生成是由于制冷剂相通过水合物层扩散到水相中形成的 .利用显微实验的生成图像计算了水合物晶体的生长速率 ,并与外冷实验中的晶体生长速率比较 ,认为扰动增大了制冷剂相和水相的两相相界面的接触维数 .Macroscopic and microscopic morphology of the formation of HCFC-141b gas hydrate were obtained by a set of low temperature experiments. The macroscopic morphology was recorded by a digital video camera, and the microscopic morphology was recorded by a microscope with a camera, magnified by 200 times. The test results indicated that the nucleation of gas hydrate had started at the two interfaces: between liquid water and liquid refrigerant or between liquid water and vapor refrigerant. The nucleation then gradually expanded to the whole boundary and formed a layer of hydrate. After that, refrigerant liquid diffused continuously into water through hydrate layer and formed new hydrate. The growth rate of gas hydrate was obtained from the microscopic photos and was compared with that in the former extermal cooling experiment. It was shown that disturbances could enhance the contact dimension between refrigerant and water phases.

关 键 词：HCFC-141b制冷剂 气体水合物 生长过程 形态 宏观图像 微观图像 生长速率 界面维数 

分 类 号：TB64[一般工业技术—制冷工程]