计算机模拟等色点—平衡移动法对配位平衡的研究  

COMPUER SIMULATION TAKEA SUPPORTING ROLE IN STUDYING COORDIATE EQUILIBRIA BY THE ISOSBESTIC POINTS—EQUILIBRIUM SHIFT METHOD

作　　者：买光昕 吕时群 宋立国 王淑仁 

出　　处：《菏泽师专学报》1991年第4期1-6,共6页

摘　　要：本文利用计算机模拟溶液平衡法,将逐级配合物相互交错的配位平衡分解为各自独立的单一平衡,给出控制的实验参数,可方便地用于配位显色反应的等色点,并配合等色点—平衡移动法测得配合物稳定常数。In this paper,computer is used to simulate the solution equilibr- ium,so the overlapping stepwise equilibria can be resolved into single equilibrium and the data of experimental conditions can be given.Because this,the isosbestie points of a coordinate reaction can be obtained easily,aud the stepwise stability constants of complexes cau be cac-ulated through experim ental data by the isosdesfic points- equilibriu shift method.

关 键 词：等色点 平衡移动 配位平衡 计算机 

分 类 号：O641.4[理学—物理化学]