金(I)化合物中的亲金相互作用  

Aurophilicity in Gold(I) Species

作　　者：欧阳一夫 刘畅[1] 于航[1] 于乐飞 OUYANG Yi-Fu;LIU Chang;YU Hang;YU Le-Fei(College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China)

机构地区：[1]北京大学化学与分子工程学院,北京100871

出　　处：《大学化学》2017年第2期79-88,共10页University Chemistry

摘　　要：20世纪80年代,人们发现在金(I)化合物的金原子之间存在某种相互作用,并称之为亲金相互作用。通过对这类化合物的深入研究,目前人们已经可以解释它们的形成原因、作用机理,以及理论依据。本文综述了亲金相互作用的发现、历史进展、典型实例,介绍了它们在物理、化学领域中的最新进展和应用。In the 1980s, interaction between gold atoms in gold(I) species was discovered, which is afterwards named“aurophilicity”. Based on in-depth researches conducted on these compounds, chemists are able to explain the reason for formation, the interacting mechanism and the theoretical foundation of them. This article reviews on the discovery of“aurophilicity”, its historical development with typical examples, and its fresh applications in branches of physics and chemistry.

关 键 词：亲金相互作用 电子相关 磷光 非线性光学 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]