Synthesis and Catalytic Performance of Environmental Friendly Co(Salen) Complex  

作　　者：Fan Huiyang Gan Ning Tao Qiong Bao Xuhui Liu Yanping 

机构地区：[1]College of Marine Science and Technology,Zhejiang Ocean University

出　　处：《Meteorological and Environmental Research》2016年第4期64-66,共3页气象与环境研究（英文版）

摘　　要：Schiff base was synthesized by using salicylaldehyde and ethylenediamine as raw materials,and then Co(Salen)complex was synthesized by using Schiff base and Co.The structure and purity of the samples were tested by mass spectrum.Then the orthogonal test method was used to study the catalytic performance of the complex in the reaction of benzil produced from benzoin,and the optimal reaction conditions were obtained finally.The results showed when the reaction temperature was 80℃,and the reaction time was 2h,the yield of benzil produced from benzoin by using Co(Salen)as catalyst reached the maximum 37.28%.Schiff base was synthesized by using salicylaldehyde and ethylenediamine as raw materials,and then Co(Salen)complex was synthesized by using Schiff base and Co.The structure and purity of the samples were tested by mass spectrum.Then the orthogonal test method was used to study the catalytic performance of the complex in the reaction of benzil produced from benzoin,and the optimal reaction conditions were obtained finally.The results showed when the reaction temperature was 80℃,and the reaction time was 2h,the yield of benzil produced from benzoin by using Co(Salen)as catalyst reached the maximum 37.28%.

关 键 词：SCHIFF base Co(Salen) COMPLEX Oxidation of BENZOIN BENZYL China 

分 类 号：TQ426[化学工程]