Extracting reaction mechanism analysis of Zn and Si from zinc oxide ore by NaOH roasting method  

作　　者：CHEN Bing SHEN Xiao-yi GU Hui-min SHAO Hong-mei ZHAI Yu-chun MA Pei-hua 陈兵;申晓毅;顾惠敏;邵鸿媚;翟玉春;马培华

机构地区：[1]School of Metallurgy,Northeastern University,Shenyang 110819,China [2]Science and Technology Laboratory,Academy of Environmental Sciences,Panjin 124010,China [3]Liaoning Key Laboratory for Metallurgical Sensor and Technology,Northeastern University,Shenyang 110819,China

出　　处：《Journal of Central South University》2017年第10期2266-2274,共9页中南大学学报（英文版）

基　　金：Projects(51774070,51204054)supported by the National Natural Science Foundation of China;Project(N150204009)supported by the Ministry of Education Basic Scientific Research Business Expenses,China;Project(2007CB613603)supported by the National Basic Research Program of China

摘　　要：The orthogonal test was used to optimize the reaction conditions of roasting zinc oxide ore with NaOH aiming to comprehensively utilize zinc oxide ore.The optimized reaction conditions were molar ratio of NaOH to zinc oxide ore 6:1,roasting temperature 450°C,holding time 150 min.The molar ratio of NaOH to zinc oxide ore was the most predominant factor affecting the extraction ratios of zinc oxide and silica.The mineral phase transformations were investigated by testing the phases of specimens obtained at different temperatures.The process was that silica reacted with molten NaOH to form Na_2SiO_3 at first,then transformed into Na_4SiO_4 with temperature rising.ZnCO_3 and its decomposing product ZnO reacted with NaOH to form Na_2ZnO_2.Na_2ZnSiO_4was also obtained.The reaction rate was investigated using unreacted shrinking core model.Two models used were chemical reaction at the particle surface and diffusion through the product layer.The results indicated that the reaction rate was combine-controlled by two models.The activation energy and frequency factor were obtained as 24.12 k J/mol and 0.0682,respectively.The orthogonal test was used to optimize the reaction conditions of roasting zinc oxide ore with NaOH aiming to comprehensively utilize zinc oxide ore.The optimized reaction conditions were molar ratio of NaOH to zinc oxide ore 6:1,roasting temperature 450°C,holding time 150 min.The molar ratio of NaOH to zinc oxide ore was the most predominant factor affecting the extraction ratios of zinc oxide and silica.The mineral phase transformations were investigated by testing the phases of specimens obtained at different temperatures.The process was that silica reacted with molten NaOH to form Na_2SiO_3 at first,then transformed into Na_4SiO_4 with temperature rising.ZnCO_3 and its decomposing product ZnO reacted with NaOH to form Na_2ZnO_2.Na_2ZnSiO_4was also obtained.The reaction rate was investigated using unreacted shrinking core model.Two models used were chemical reaction at the particle surface and diffusion through the product layer.The results indicated that the reaction rate was combine-controlled by two models.The activation energy and frequency factor were obtained as 24.12 k J/mol and 0.0682,respectively.

关 键 词：zinc oxide ORE NAOH ROASTING METHOD REACTION process REACTION mechanism kinetics 

分 类 号：TF813[冶金工程—有色金属冶金] TQ127.2[化学工程—无机化工]