HZSM-5催化酯化反应的实验教学改进研究  

Research on the Experimental Teaching Improvement of HZSM-5 in Esterification Reaction

作　　者：李福颖[1,2] 牛玉[1,2] 张丽华[1,2] 王仁章[1,2] LI Fu-ying;NIU Yu;ZHANG Li-hua;WANG Ren-zhang(College of Resources and Chemical Engineering, Sanming University;Collaborative Innovation Center of Clean Coal Gasification Technology, Sanming University, Fujian Sanming, 365004)

机构地区：[1]三明学院资源与化工学院 [2]三明学院2011洁净煤气化技术协同创新中心,福建三明365004

出　　处：《漳州职业技术学院学报》2017年第4期77-80,共4页Journal of Zhangzhou Institute of Technology

基　　金：教育部化工专业卓越工程师人才培养计划专项(20080591);三明学院高等教育教学改革项目(J1610516;J1419)

摘　　要：酯化反应是基础有机化学实验教学中重要的实验内容之一。传统的酯化反应实验以浓硫酸为催化剂,操作复杂、危险性高、产率低。为简化操作程序、降低实验危险、提高生成物产率,以合成乙酸正丁酯反应为例,使用HZSM-5固体酸代替浓硫酸为催化剂进行酯化反应探索,结果表明:该催化剂具有稳定性好、操作简便、成本低、安全无毒和可重复使用等优点。该实验使学生直观感受到绿色化学的现实意义,对树立学生环保意识具有非常好的促进作用。Esterification reaction was one of the most important experimental contents in basic organic chemistry experiment teaching.The traditional esterification reaction was characterized by concentrated sulfuric acid as catalyst,which was complex,high risk and low yield.In order to simplify operating procedures,reduce the risk of experiment and improve the yield of production,taking the synthesis of butyl acetate as an example,the HZSM-5solid acid was used to replace sulfuric acid as catalyst for esterification reaction.Results showed that the catalyst had the advantages of good stability,simple operation,low cost,safe and non-toxic and reusable.The experiment made the students feel the practical significance of green chemistry and promote the students'environmental awareness.

关 键 词：HZSM-5固体酸 酯化反应 教学改进 绿色化学 

分 类 号：TQ032.4[化学工程]