苯甲酸类化合物的绿色合成  

Green Synthesis of Benzoic Acid Derivatives

作　　者：杨雪 田源[1] 于笑寒 王宏胜[1] 李公春[1] YANG Xue;TIAN Yuan;YU Xiao-han;WANG Hong-sheng;LI Gong-chun(College of Chemistry and Chemical Engineering,Xuchang University,Xuchang 461000,China;College of Advanced Materials Energy,Xuchang University,Xuchang 461000,China)

机构地区：[1]许昌学院化学化工学院,河南许昌461000 [2]许昌学院新材料与能源学院,河南许昌461000

出　　处：《安徽化工》2019年第1期33-35,共3页Anhui Chemical Industry

基　　金：河南省高等学校重点科研项目(项目编号:16A150062);许昌学院科研基金项目(项目编号:2018YB011)

摘　　要：在钨酸钠、磺基水杨酸和十六烷基三甲基溴化铵催化下,以苯甲醛类化合物为原料,用30%过氧化氢作为氧化剂,合成了苯甲酸类化合物。研究了反应时间、过氧化氢用量和催化剂对苯甲醛氧化合成苯甲酸反应产率的影响,给出了绿色合成苯甲酸类化合物方法,得到了六个苯甲酸类化合物。Benzoic acid compounds were synthesized by sodium tungstic and sulfosalicylic acid catalyzed oxidation benzaldehyde compounds with 30%hydrogen peroxide in the presence of hexadecyl trimethyl ammonium bromide as a phase transfer catalyst.The synthesis reaction of benzoic acid was discussed,the effects of reaction time,hydrogen peroxide dosage and catalyst on reaction yield were studied.The method of green synthesis of was given through experiment,six benzoic acid compounds were synthesized.

关 键 词：苯甲醛类化合物 苯甲酸类化合物 过氧化氢 绿色合成 

分 类 号：TQ245[化学工程—有机化工]