Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction  

作　　者：WANG Ying WANG Qiliao HOU Liman ZHOU Mingdong DONG Dewen ZHANG Ning 

机构地区：[1]School of Chemistry and Materials Science,Liaoning Shihua University,Fushun 113001,P.R,China [2]CAS Key Laboratory of High-performance Synthetic Rubber and Its Composite Materials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,P.R.China [3]University of Science and Technology of China,Hefei 230026,P.R.China

出　　处：《Chemical Research in Chinese Universities》2019年第2期340-344,共5页高等学校化学研究（英文版）

摘　　要：Poly(ethylene phosphonate)was synthesized via the living ring-opening polymerization of cyclic phos-phonate monomer catalyzed by organocatalyst.The pendant vinyl ftmctionalities were employed to perform the pho-tochemical click reactions wi&tMols.We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains,enabling the rapid and efficient functionalization of polyphos-phoesters(PPE).

关 键 词：Cyclic PHOSPHONATE RING-OPENING polymerization THIOL-ENE click reaction Post modification 

分 类 号：O6[理学—化学]