一种聚氨酯型高分子染料的制备及皮革涂层着色性能研究  

Preparation of polyurethane based polymer dye and coloring properties of leather coating

作　　者：王新科 强西怀 丁志文[3] 张悦[3] WANG Xinke;QIANG Xihuai;DING Zhiwen;ZHANG Yue(College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science and Technology,Xi'an 710021,China;National Demonstration Center for Experimental Light Chemistry Engineering Education,Shaanxi University of Science and Technology,Xi'an 710021,China;China Leather and Footwear Industry Research Institute,Beijing100016,China)

机构地区：[1]陕西科技大学轻工科学与工程学院,西安710021 [2]陕西科技大学轻化工程国家级实验室教学示范中心,西安710021 [3]中国皮革和制鞋工业研究院,北京100016

出　　处：《功能材料》2019年第4期4192-4196,共5页Journal of Functional Materials

基　　金：国家重点研发计划资助项目(2017YFB0308500);陕西科技大学创新科研团队资助项目(TD12-04)

摘　　要：用2,4-甲苯二异氰酸酯(TDI)、聚丙二醇1000(PPG-1000)和2,2-二羟甲基丙酸(DMPA)合成聚氨酯聚合体,再用酸性红B染料进行封端,制备了一种聚氨酯型高分子染料。通过傅立叶红外光谱对其结构进行了表征,并测定了这种聚氨酯型染料分散乳液的粒径分布,最后对坯革进行着色涂饰实验。结果表明,用含单羟基活性基团的酸性红B染料对端异氰酸酯大分子进行封端处理,能够实现染料与聚氨酯大分子的结合,可以衍生制得聚氨酯型高分子染料;在制备反应过程中,预聚反应最佳R比值为3∶1,聚合反应体系总R值为1.1,这种聚氨酯型大分子染料乳液分散体系的粒径主要分布在80～160μm之间;采用聚氨酯染料作为着色材料对坯革表面进行涂饰操作,其坯革涂层耐干湿擦色牢度、耐洗色牢度和耐色迁移性的色牢度极佳,均达到了5级,均明显高于酸性红B染料的着色涂层。A red waterborne polyurethane-based dye was successfully synthesized by importing the acid red B into the polyurethane chain ends via the reaction of the polymerition of 2,4-toluene diisocyanate(TDI),polypropylene glycol1000(PPG-1000)and 2,2-dimethylolpropionic acid(DMPA).The structure was characterized by Fourier transform infrared spectroscopy(FT-IR),the particle size distribution of the polyurethane disperse emulsion was measured,and the finishing experiments of crust leather were conducted.The optimal R value of the prepolymerization was 3∶1 and the total R value of the polymerization was1.1 in the polymerization process.The particle size of the polyurethane disperse emulsion mainly distributed in 80-160μm.The dry&wet rubbing fastness,the washing fastness and the colour fastness to migration of the crust leather coating by the treatment of the polymeric dye excellently reached 5 level,which were higher than those of the acid red B coloring coating.

关 键 词：酸性红B 聚氨酯 高分子染料 涂饰 皮革 

分 类 号：TS61[轻工技术与工程]