PPO-PEO-PPO长链脂肪酸聚醚酯的合成及消泡、乳化性能研究  

Studies on Synthesis, Defoaming and Emulsifying Properties of PPO-PEO-PPO Long Chain Aliphatic Acid Polyether Ester

作　　者：岳森 穆文庆 李莉 李欢玲 Yue Sen;Mu Wenqing;Li Li;Li Huanling(Guangdong Provincial Key Laboratory of Industrial Surfactant,Guangzhou 510665;Guangdong Research Institute of Petrochemical andFine Chemical Engineering,Guangzhou 510665;Guangdong University of Technology,Guangzhou 510006,China)

机构地区：[1]广东省工业表面活性剂重点实验室,广东广州510665 [2]广东省石油与精细化工研究院,广东广州510665 [3]广东工业大学,广东广州510006

出　　处：《广东化工》2019年第20期3-5,共3页Guangdong Chemical Industry

基　　金：项目名称：广州市科技计划功能性聚醚酯的研究开发，项目编号：201707010383

摘　　要：选择六种聚醚(PEP-1、PEP-2、PEP-3、PEP-4、SDR-40和L44)和芥酸进行酯化反应,确定最佳反应条件是复合催化剂用量5 mol%,在130℃下反应6h即可;同时研究产物的表面张力、泡沫性能和乳化性能,表明含有PEAE-2或PEAE-SDR40的乳液粒径更加小而均匀,乳化性能突出,消泡能力也最好。Six kinds of polyethers (PEP-1, PEP-2, PEP-3, PEP-4, SDR-40 and L44) and erucic acid were selected for esterification, and the optimum reaction conditions were determined as follows: composite catalyst (C/D=2/1), dosage 5 mol%, reaction at 130 ℃ for 6 h. At the same time, the surface tension, foam properties and emulsification properties of the products were studied, which showed that the emulsion containing PEAE-2 or PEAE-SDR40 had smaller and uniform particle size, outstanding emulsification and defoaming ability.

关 键 词：聚醚 脂肪酸 聚醚酯 表面张力 消泡 乳化 

分 类 号：TQ[化学工程]