The xanthate route to all-carbon quaternary centers  

作　　者：Béatrice Quiclet-Sire Samir Z.Zard 

机构地区：[1]Laboratoire de Synthèse Organique, Ecole Polytechnique

出　　处：《Science China Chemistry》2019年第11期1450-1462,共13页中国科学（化学英文版）

基　　金：Ecole Polytechnique;CNRS;DGA;MNRT;The Fondation Alfred Kastler;the Royal Commission for the Exhibition of 1851;the China Research Council;Aventis(now Sanofi);Rhodia(now Solvay);Syngenta

摘　　要：This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. Itsummarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radicaladditions and combinations thereof that have so far been used to construct quaternary centers.This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra-and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

关 键 词：XANTHATES QUATERNARY CENTERS RADICAL addition CYCLIZATION tandem reactions 

分 类 号：O62[理学—有机化学]