Radical cascade reactions of unsaturated C–C bonds involving migration  

作　　者：Ge Zhang Yang Liu Jinbo Zhao Yan Li Qian Zhang 

机构地区：[1]Jilin Province Key Laboratory of Organic Functional Molecular Design&Synthesis,Department of Chemistry,Northeast Normal University,Jilin 130024,China [2]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Science China Chemistry》2019年第11期1476-1491,共16页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(21831002,21801039);Ten Thousand Talents Program,the Jilin Province Natural Science Foundation(20160519003JH);the Fundamental Research Funds for the Central Universities(2412018QD007)

摘　　要：During the past few years, with the rapid development of mild methods for the generation of radical species, great progress in radical cascade reactions of unsaturated C–C bonds has been made. Many radical cascade reactions involve functional groups migration, which leads structurally much more diverse, complex and valuable compounds not easily obtained through other methods. In this review, the recent achievements in unsaturated C–C bonds radical cascade reactions involving migration are summarized.During the past few years, with the rapid development of mild methods for the generation of radical species, great progress in radical cascade reactions of unsaturated C–C bonds has been made. Many radical cascade reactions involve functional groups migration, which leads structurally much more diverse, complex and valuable compounds not easily obtained through other methods. In this review, the recent achievements in unsaturated C–C bonds radical cascade reactions involving migration are summarized.

关 键 词：RADICAL CASCADE reaction functional group MIGRATION UNSATURATED C–C BONDS C-centered RADICALS N-centered RADICALS 

分 类 号：O62[理学—有机化学]