Poly(phenylene oxide) and Renewable Polyamide 11 Blends Compatibilized by Ethylene-n-Octene Copolymer  

作　　者：Regina Jeziorska Agnieszka Abramowicz Agnieszka Szadkowska Anna Pasnik Ewa Spasowka 

机构地区：[1]Department of Polymer Technology and Processing,Industrial Chemistry Research Institute,Rydygiera 8,01-793 Warsaw,Poland

出　　处：《Journal of Renewable Materials》2018年第7期772-783,共12页可再生材料杂志（英文）

摘　　要：Poly(phenylene oxide)/renewable polyamide 11 (PPO/PA11 20/80) blends toughened with glycidylmethacrylate grafted ethylene-n-octene copolymer (GEOC) were prepared in a co-rotating twin-screwextruder. The reaction between GEOC and PPO/PA11 blend was analyzed by gel content tests. Themorphology of PPO/PA11/GEOC blends was observed by scanning electron microscope. The SEMresults showed that PPO formed the continuous phase, though it is a minority component of blends. Withincreasing GEOC content from 5 to 15 wt% the morphology of the blends transformed from droplet-matrix toco-continuous structure, in which both PA11 and PPO phases are continuous. The blend with co-continuousmorphology had better mechanical properties than those with droplet-matrix morphology. The impactstrength of the PPO/PA11/GEOC blends was much higher compared to the one without GEOC as well asPA11 due to the compatibilizing effect, which was also proved by DSC analysis, rheological behavior (MFR,DMTA) and tensile properties.

关 键 词：COMPATIBILIZATION elastomer PPO/PA11 blends TOUGHENING 

分 类 号：TQ3[化学工程]