基于相平衡与化学动力学的综合实验教学  

Comprehensive Experiment Teaching on Phase Equilibrium and Chemical Kinetics

作　　者：黄维佳 唐洁 李云[2] 孙丽[1] 苏文献[1] HUANG Wei-Jia;TANG Jie;LI Yun;SUN Li;SU Wen-Xian(School of Energy and Power Engineering,University of Shanghai for Science and Technology,Shanghai 200093,China;School of Environment and Architecture,University of Shanghai for Science and Technology,Shanghai 200093,China)

机构地区：[1]上海理工大学能源与动力工程学院,上海200093 [2]上海理工大学环境与建筑学院,上海200093

出　　处：《化学教育（中英文）》2020年第2期61-64,共4页Chinese Journal of Chemical Education

基　　金：国家自然科学基金项目(51706146,51741605);上海市青年科技英才扬帆计划(19YF1434800);上海理工大学教师教学发展研究项目(CFTD191001)。

摘　　要：介绍了一个综合性物理化学实验:赖氨酸钠溶液吸收CO2的气液相平衡与化学动力学。针对物理化学中相平衡和化学动力学2章内容,开展实验教学。本实验以易得的赖氨酸、氢氧化钠和CO2为原材料,通过试剂配制、气液吸收和数据采集等实验操作,分析得到赖氨酸钠-CO2体系的相平衡数据(温度、压力、溶解度)和吸收过程的化学动力学特性(表观速率常数)。结合基本参数测量(质量、温度、压力与时间等)和热力学与动力学函数计算,既提高学生的综合实验能力,又加强其对多章节知识点的融会贯通,激发其科研兴趣和探索精神。A comprehensive experiment of physical chemistry was introduced to measure and calculate the vapor-liquid equilibrium and chemical kinetics of the sodium lysine-CO2 system,which is related to two chapters,phase equilibrium and chemical kinetics,in the course of physical chemistry.L-Lysine,sodium hydroxide,and CO2 were used in this experiment,including the operations of reagent preparing,gas absorption,and data acquisition.Phase equilibrium parameters(temperature,pressure,and solubility)and chemical kinetics properties(apparent rate constant)were calculated and analyzed,to improve the operation ability of students,enhance their understanding of the course knowledge,and inspire their exploration on scientific research.

关 键 词：二氧化碳 赖氨酸钠 气液相平衡 吸收动力学 溶解度 表观速率常数 

分 类 号：G642[文化科学—高等教育学] O64-4[文化科学—教育学]