Au nanospheres modified boron-doped diamond microelectrode grown via hydrogen plasma etching solid doping source for dopamine detection  

作　　者：Kaili Yao Xiaojun Tan Bing Dai Jie Bai Qiaoyang Sun Wenxin Cao Jiwen Zhao Lei Yang Jiecai Han Jiaqi Zhu 

机构地区：[1]National Key Laboratory of Science and Technology on Advanced Composites in Special Environments,Harbin Institute of Technology,Harbin,150080,China

出　　处：《Journal of Materials Science & Technology》2020年第14期42-46,共5页材料科学技术（英文版）

基　　金：financially supported by the National Science Fund for Distinguished Young Scholars(No.51625201);the National Natural Science Foundation of China No.51,702,066;the National Key Research and Development Program of China(No.2016YFE0201600);the Key Laboratory of Micro-systems and Micro-structures Manufacturing,Ministry of Education,Harbin Institute of Technology(No.2016KM001);the Innovative research group of NSFC11421091。

摘　　要：Boron doped diamond(BDD)electrode is a promising electrochemical material for detecting dopamine level in the human’s body.In this work,we developed a new doping source-graphite and solid boron oxide powders to synthesize BDD film with microwave plasma chemical vapor deposition,so as to avoid using toxic or corrosive dopants,such as boroethane and trimethylborate.The synthesized BDD film is pinhole free and with high doping density of 8.44×10^20 cm^-3 calculated from the Raman spectroscopy.Subsequently,Au nanospheres were decorated on the surface of BDD film to improve electrochemical performance of the BDD film.The Au nanoparticles modified BDD electrode demonstrates an excellent electrochemical response,a high sensitivity(in the range of 5μM-1 m M),and a low detection limit(~0.8μM)for detecting dopamine.

关 键 词：Boron doped diamond Graphite powders Boron oxide powders Optical emission spectroscopy DOPAMINE 

分 类 号：TB34[一般工业技术—材料科学与工程]