石墨烯玻璃的制备与应用  

Preparation and application of graphene glass

作　　者：单俊杰 崔凌智 周帆 张艳锋[1,2,4] 刘忠范 Junjie Shan;Lingzhi Cui;Fan Zhou;Yanfeng Zhang;Zhongfan Liu(Center for Nanochemistry,Beijing National Laboratory for Molecular Sciences,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;Beijing Graphene Institute,Beijing 100095,China;Academy for Advanced Interdisciplinary Studies,Peking University,Beijing 100871,China;Department of Materials Science and Engineering,College of Engineering,Peking University,Beijing 100871,China)

机构地区：[1]北京大学化学与分子工程学院,纳米化学研究中心,北京分子科学国家研究中心,北京100871 [2]北京石墨烯研究院,北京100095 [3]北京大学前沿交叉学科研究院,北京100871 [4]北京大学工学院,材料科学与工程系,北京100871

出　　处：《中国科学：化学》2020年第10期1422-1438,共17页SCIENTIA SINICA Chimica

基　　金：国家重点研发计划(编号:2016YFA0200103,2018YFA0703700);国家自然科学基金(编号:51520105003,51432002,51991344,51925201);北京市自然科学基金(编号:Z181100004818002,Z191100000819004);北京分子科学国家研究中心(BNLMS-CXTD-202001)资助项目。

摘　　要：石墨烯在结构及性能上的独特优势赋予了其在现代科学和技术领域不可替代的作用.高品质石墨烯的可控制备及杀手锏级应用方向的开拓,是推动石墨烯产业化进程的关键环节.在石墨烯的无损转移技术无法取得突破性进展的前提下,在功能性绝缘基底表面实现高质量石墨烯的直接可控生长并发展其独特的应用,为石墨烯的产业化应用提供了新的思路/方向.在玻璃基底上直接生长石墨烯,可整合石墨烯优异的透明/导电特性与玻璃广泛的用途,在基础科学及实际应用中均具有很高的研究价值.本课题组在国际上率先提出"超级石墨烯玻璃"的概念,经多年的努力,在石墨烯玻璃的制备及应用研究中取得一系列重要进展.本文从玻璃基底上直接生长石墨烯面临的挑战出发,综述了不同种类玻璃基底上石墨烯的生长方法与基本物性,以及在应用方面取得的最新研究进展,最后展望了石墨烯玻璃未来的发展方向.Numerous excellent characteristics of graphene endow it an irreplaceable role in modern science and technology. The controllable preparation and application exploration of high-quality graphene are the key to the industrialization of graphene. In the premise that no breakthrough can be made in the nondestructive transfer technique,the directly controllable growth of high-quality graphene on the surface of functional insulating substrate provides a new idea and direction for the industrialized application of graphene in the future. The direct growth of graphene on glass substrate can integrate the excellent characteristics of graphene and the wide applications of glass, which is of significant research value in both basic science and practical applications. The concept of "super graphene glass" was first proposed by Liu’s group of Peking University, and through years of efforts, a series of significant advances have been achieved in the preparation and application of graphene/glass. The technical challenge for the direct growth of graphene on glass substrate, the growth mechanism and basic physical properties of graphene on different glass substrates are reviewed,and the latest research advances in application of graphene/glass are summarized. Finally, the development directions of graphene/glass in the future are prospected.

关 键 词：石墨烯 玻璃 化学气相沉积 等离子体辅助 智能窗 

分 类 号：TQ127.11[化学工程—无机化工]