纤维素基纸表面疏水改性研究进展  

Progress in Hydrophobic Modification on the Surface of Cellulose-based Paper

作　　者：王超 高海龙 陈晓倩[2] 倪书振 刘娜[2] 戴红旗[4] WANG Chao;GAO Hai-long;CHEN Xiao-qian;NI Shu-zhen;LIU Na;DAI Hong-qi(Shandong Henglian New Material Co.,Ltd,Weifang 261000,China;State Key Laboratory of Biobased Material and Green Papermaking,Qilu University of Technology,Shandong Academy of Sciences,Jinan 250353,China;Shandong Industrial Technician College,Weifang 261000,China;Department of Pulp and Paper Science and Technology,Nanjing Forestry University,Nanjing 210037,China)

机构地区：[1]山东恒联新材料股份有限公司,山东潍坊261000 [2]齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,山东济南250353 [3]山东工业技师学院,山东潍坊261000 [4]南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京210037

出　　处：《纤维素科学与技术》2020年第4期63-73,共11页Journal of Cellulose Science and Technology

基　　金：江苏省科技计划重大项目(BE2018129);山东省重点研发项目(2016GGX108002);青年博士合作基金项目(2018BSHZ0015)。

摘　　要：疏水性能作为纸张的一个重要指标,与其应用性能息息相关。由于传统的浆内法添加疏水试剂的改性方式不利于其与纤维结合,对成纸的疏水性能改善效果较为有限,因此纸张表面疏水改性的研究日益增长。首先从传统的涂布法对赋予纸张表面疏水性的研究现状进行了综述,然后介绍了化学法和物理-化学法对纤维疏水改性的研究现状,最后重点阐述了采用纳米技术和可降解生物聚合物在疏水改性中的研究进展。综述内容将为造纸工作者研究更为有效、环境友好和成本低廉的纸页表面疏水改性方法,提升和拓展纸基材料的应用性能起到积极的促进作用。As an important indicator of papers,the hydrophobicity is closely related with its application performance.The traditional addition manner for the hydrophobic chemicals in pulp is not conductive for its bonding with the fibers,which leads to the limited hydrophobicity performance.Thus,the research on the hydrophobic modification of paper surface is increasing.This paper firstly introduced the traditional hydrophobic modification approachcoating method.Then,the research stated the chemical method and physical-chemical method.The emphasis is placed on using nanotechnology and degradable biopolymer to enhance the hydrophobicity.This review would play a positive role in the research of improving the hydrophobicity of papers through a more efficient,environmentfriendly and low-cost way,as well as improving and broadening the application performance of the paper-based materials.

关 键 词：纤维素基纸 表面疏水性 化学法 物理化学法 纳米技术 

分 类 号：TS7[轻工技术与工程—制浆造纸工程]