气相色谱-串联质谱法测定三七中腐霉利残留量的不确定度评定  

Uncertainty evaluation for the determination of procymidone residues in Panax notoginseng by gas chromatography tandem mass spectrometry

作　　者：李彦生[1] 董寿堂[2] 柴连周[2] 鲁静[2] LI Yan-Sheng;DONG Shou-Tang;CHAI Lian-Zhou;LU Jing(Yunnan Center for Disease Control and Prevention,Kunming 650022,China;Baoshan College of Traditional Chinese Medicine,Baoshan 678000,China)

机构地区：[1]云南省疾病预防控制中心,昆明650022 [2]保山中医药高等专科学校,保山678000

出　　处：《食品安全质量检测学报》2020年第23期8920-8924,共5页Journal of Food Safety and Quality

基　　金：保山中医药高等专科学校科技创新团队项目(2020t001)。

摘　　要：目的评定气相色谱串联质谱法测定三七中腐霉利残留量的不确定度。方法根据JJF1059.1-2012《测量不确定度评定与表示》,采用气相色谱串联质谱法测定三七中腐霉利残留量,计算各不确定度的分量,合成标准不确定度,得到扩展不确定度,并分析检测方法中不确定度的来源。结果三七样品中腐霉利残留量为0.103 mg/kg时,扩展不确定度为0.005 mg/kg(k=2)。结论测定三七样品中腐霉利的不确定度主要来源于标准溶液的配制过程和标准曲线的拟合。Objective To evaluate the uncertainty of the determination of procymidone residues in Panax notoginseng by gas chromatography tandem mass spectrometry.Methods According to JJF 1059.1-2012 Measurement uncertainty evaluation and presentation,the procymidone residues in Panax notoginseng was measured by gas chromatography tandem mass spectrometry,the component of each uncertainty was calculated and the standard uncertainty was synthesized to obtain the extended uncertainty.The source of uncertainty was analyzed in testing procedure.Results When the residues of procymidone in Panax notoginseng was 0.103 mg/kg,the extended uncertainty was 0.005 mg/kg(k=2).Conclusion The uncertainties of the determination of procymidone are mainly derived from the standard solution preparation process and standard curve fitting.

关 键 词：气相色谱-串联质谱法 三七 腐霉利 不确定度 

分 类 号：R284[医药卫生—中药学] O657.63[医药卫生—中医学]